University of Hamburg, Institute for Nanostructure and Solid State Physics, Center for Hybrid Nanostructures (CHyN), Luruper Chaussee 149, Building 600, 22761 Hamburg, Germany.
Nanoscale Horiz. 2020 Mar 1;5(3):431-453. doi: 10.1039/c9nh00380k. Epub 2019 Dec 11.
Motivated by the air pollution that skyrocketed in numerous regions around the world, great effort was placed on discovering new classes of materials that separate, sense or convert CO in order to minimise impact on human health. However, separation, sensing and conversion are not only closely intertwined due to the ultimate goal of improving human well-being, but also because of similarities in material prerequisites -e.g. affinity to CO. Partly inspired by the unrivalled performance of complex natural materials, manifold inorganic-organic hybrids were developed. One of the most important characteristics of hybrids is their design flexibility, which results from the combination of individual constituents with specific functionality. In this review, we discuss commonly used organic, inorganic, and inherently hybrid building blocks for applications in separation, sensing and catalytic conversion and highlight benefits like durability, activity, low-cost and large scale fabrication. Moreover, we address obstacles and potential future developments of hybrid materials. This review should inspire young researchers in chemistry, physics and engineering to identify and overcome interdisciplinary research challenges by performing academic research but also - based on the ever-stricter emission regulations like carbon taxes - through exchanges between industry and science.
受世界各地许多地区的空气污染飙升的影响,人们努力发现新的材料类别,以分离、感知或转化 CO,从而将对人类健康的影响降到最低。然而,由于提高人类福祉是最终目标,因此分离、感应和转换不仅密切交织在一起,而且由于材料前提条件的相似性,例如对 CO 的亲和力。部分受复杂天然材料无与伦比的性能的启发,开发了多种无机-有机杂化材料。杂化材料的一个最重要特征是其设计灵活性,这源于具有特定功能的单个成分的组合。在这篇综述中,我们讨论了常用于分离、传感和催化转化应用的常用有机、无机和固有杂化构建块,并强调了耐用性、活性、低成本和大规模制造等优势。此外,我们还讨论了混合材料的障碍和潜在的未来发展。这篇综述应该激励化学、物理和工程领域的年轻研究人员通过学术研究来识别和克服跨学科研究的挑战,并且——基于像碳税这样的日益严格的排放法规——通过工业和科学之间的交流来克服这些挑战。