CALAGUA - Unidad Mixta UV-UPV, Instituto de Ingeniería del Agua y Medio Ambiente - IIAMA, Universitat Politècnica de València, Camí de Vera s/n, 46022 València, Spain.
CALAGUA - Unidad Mixta UV-UPV, Departament d'Enginyeria Química, Universitat de València, Avinguda de la Universitat s/n, 46100 Burjassot, València, Spain.
Water Res. 2020 May 15;175:115647. doi: 10.1016/j.watres.2020.115647. Epub 2020 Feb 24.
As phosphorus is a non-renewable resource mainly used to produce fertilizers and helps to provide food all over the world, the proper management of its reserves is a global concern since it is expected to become scarcer in the near future. In this work we assessed two different sludge line configurations aiming for P extraction and recovery before anaerobic digestion and compared them with the classical configuration. This study has been performed by simulation with the model BNRM2 integrated in the software package DESASS 7.1. Configuration 1 was based on the production of a PO-enriched stream from sludge via elutriation in the primary thickeners, while Configuration 2 was based on the WASSTRIP® process and its PO-enriched stream was mechanically obtained with dynamic thickeners. In both alternatives recovery was enhanced by promoting poly-phosphate (poly-P) extraction under anaerobic conditions, for which both configurations were fully evaluated in a full-scale WWTP. Both were also optimized to maximize phosphorus extraction. Their costs and life cycles were also analysed. The novelty of this research lies in the lack of literature about the integral evaluation of pre-anaerobic digestion P recovery from wastewaters. This study included a holistic approach and an optimization study of both alternatives plus their economic and environmental aspects. In Configuration 1, the PO-P load in the recovery stream reached 43.1% of the total influent P load and reduced uncontrolled P-precipitation in the sludge line up to 52.9%. In Configuration 2, extraction was 48.2% of the influent P load and it reduced precipitation by up to 60.0%. Despite Configuration 1's lower phosphorus recovery efficiency, it had a 23.0% lower life cycle cost and a 14.2% lower global warming impact per hm of treated influent than Configuration 2. Configuration 1 also reduced the TAEC by 17.6% and global warming impact by 2.0% less than Configuration 0.
由于磷是一种不可再生资源,主要用于生产肥料,并有助于在全球范围内提供食物,因此,合理管理其储量是全球关注的问题,因为预计在不久的将来,磷将变得更加稀缺。在这项工作中,我们评估了两种不同的污泥处理线配置,旨在进行磷的提取和回收,然后进行厌氧消化,并将其与传统配置进行比较。这项研究是通过模型 BNRM2 在软件包 DESASS 7.1 中的集成进行模拟的。配置 1 基于通过初级浓缩池的淘洗从污泥中生产富含 PO 的流,而配置 2 基于 WASSTRIP®工艺,其富含 PO 的流是通过动态浓缩池机械获得的。在这两种替代方案中,通过在厌氧条件下促进多磷酸盐(poly-P)的提取来增强回收,这两种替代方案都在一个全规模的 WWTP 中进行了全面评估。两种方案都经过优化以最大限度地提取磷。还分析了它们的成本和生命周期。这项研究的新颖之处在于缺乏关于从废水中进行厌氧消化前磷回收的综合评估的文献。这项研究包括对替代方案的整体评估以及对替代方案的优化研究,以及它们的经济和环境方面。在配置 1 中,回收流中的 PO-P 负荷达到了总进水 P 负荷的 43.1%,并将污泥线中的无控制磷沉淀减少了 52.9%。在配置 2 中,提取率为进水 P 负荷的 48.2%,沉淀减少了 60.0%。尽管配置 1 的磷回收效率较低,但与配置 2 相比,其生命周期成本降低了 23.0%,每处理 hm 进水的全球变暖影响降低了 14.2%。配置 1 还将 TAEC 降低了 17.6%,全球变暖影响降低了 2.0%,而不是配置 0。