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用于锂电池的陶瓷/聚合物复合固体电解质的进展与展望

Progress and Perspective of Ceramic/Polymer Composite Solid Electrolytes for Lithium Batteries.

作者信息

Li Song, Zhang Shi-Qi, Shen Lu, Liu Qi, Ma Jia-Bin, Lv Wei, He Yan-Bing, Yang Quan-Hong

机构信息

Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate School Tsinghua University Shenzhen 518055 P. R. China.

Laboratory of Advanced Materials School of Materials Science and Engineering Tsinghua University Beijing 100084 P. R. China.

出版信息

Adv Sci (Weinh). 2020 Jan 21;7(5):1903088. doi: 10.1002/advs.201903088. eCollection 2020 Mar.

DOI:10.1002/advs.201903088
PMID:32154083
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7055568/
Abstract

Solid composite electrolytes (SCEs) that combine the advantages of solid polymer electrolytes (SPEs) and inorganic ceramic electrolytes (ICEs) present acceptable ionic conductivity, high mechanical strength, and favorable interfacial contact with electrodes, which greatly improve the electrochemical performance of all-solid-state batteries compared to single SPEs and ICEs. However, there are many challenges to overcome before the practical application of SCEs, including the low ionic conductivity less than 10 S cm at ambient temperature, poor interfacial stability, and high interfacial resistance, which greatly restrict the room temperature performance. Herein, the advances of SCEs applied in all-solid-state lithium batteries are presented, including the Li ion migration mechanism of SCEs, the strategies to enhance the ionic conductivity of SCEs by various morphologies of ICEs, and construction methods of the low resistance and stable interfaces of SCEs with both cathode and anode. Finally, some typical applications of SCEs in lithium batteries are summarized and future development directions are prospected. This work presents how it is quite significant to further enhance the ionic conductivity of SCEs by developing the novel SPEs with the special morphology of ICEs for advanced all-solid-state lithium batteries.

摘要

固态复合电解质（SCEs）结合了固态聚合物电解质（SPEs）和无机陶瓷电解质（ICEs）的优点，具有可接受的离子电导率、高机械强度以及与电极良好的界面接触，与单一的SPEs和ICEs相比，极大地提高了全固态电池的电化学性能。然而，在SCEs实际应用之前，仍有许多挑战需要克服，包括室温下离子电导率低于10 S cm、界面稳定性差以及界面电阻高，这些都极大地限制了其室温性能。本文介绍了SCEs在全固态锂电池中的研究进展，包括SCEs的锂离子迁移机制、通过ICEs的各种形态提高SCEs离子电导率的策略，以及SCEs与正负极之间低电阻和稳定界面的构建方法。最后，总结了SCEs在锂电池中的一些典型应用，并展望了未来的发展方向。这项工作表明，通过开发具有ICEs特殊形态的新型SPEs来进一步提高SCEs的离子电导率对于先进的全固态锂电池具有重要意义。

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