Suppr超能文献

全固态锂电池用有机-无机复合固体电解质的进展与挑战

Advancements and Challenges in Organic-Inorganic Composite Solid Electrolytes for All-Solid-State Lithium Batteries.

作者信息

Zhang Xueyan, Cheng Shichao, Fu Chuankai, Yin Geping, Wang Liguang, Wu Yongmin, Huo Hua

机构信息

State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, People's Republic of China.

College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310058, People's Republic of China.

出版信息

Nanomicro Lett. 2024 Sep 20;17(1):2. doi: 10.1007/s40820-024-01498-y.

Abstract

To address the limitations of contemporary lithium-ion batteries, particularly their low energy density and safety concerns, all-solid-state lithium batteries equipped with solid-state electrolytes have been identified as an up-and-coming alternative. Among the various SEs, organic-inorganic composite solid electrolytes (OICSEs) that combine the advantages of both polymer and inorganic materials demonstrate promising potential for large-scale applications. However, OICSEs still face many challenges in practical applications, such as low ionic conductivity and poor interfacial stability, which severely limit their applications. This review provides a comprehensive overview of recent research advancements in OICSEs. Specifically, the influence of inorganic fillers on the main functional parameters of OICSEs, including ionic conductivity, Li transfer number, mechanical strength, electrochemical stability, electronic conductivity, and thermal stability are systematically discussed. The lithium-ion conduction mechanism of OICSE is thoroughly analyzed and concluded from the microscopic perspective. Besides, the classic inorganic filler types, including both inert and active fillers, are categorized with special emphasis on the relationship between inorganic filler structure design and the electrochemical performance of OICSEs. Finally, the advanced characterization techniques relevant to OICSEs are summarized, and the challenges and perspectives on the future development of OICSEs are also highlighted for constructing superior ASSLBs.

摘要

为解决当代锂离子电池的局限性,特别是其低能量密度和安全问题,配备固态电解质的全固态锂电池已被视为一种很有前途的替代方案。在各种固态电解质中,结合了聚合物和无机材料优点的有机-无机复合固态电解质(OICSEs)在大规模应用方面展现出了巨大潜力。然而,OICSEs在实际应用中仍面临诸多挑战,如离子电导率低和界面稳定性差等问题,这严重限制了它们的应用。本文综述全面概述了OICSEs的最新研究进展。具体而言,系统地讨论了无机填料对OICSEs主要功能参数的影响,包括离子电导率、锂迁移数、机械强度、电化学稳定性、电子电导率和热稳定性。从微观角度深入分析并总结了OICSEs的锂离子传导机制。此外,对经典的无机填料类型进行了分类,包括惰性填料和活性填料,并特别强调了无机填料结构设计与OICSEs电化学性能之间的关系。最后,总结了与OICSEs相关的先进表征技术,并强调了构建优质全固态锂电池时OICSEs未来发展面临的挑战和前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1438/11415606/684658378688/40820_2024_1498_Fig1_HTML.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验