CEITEC-Central European Institute of Technology, Brno University of Technology, 61200 Brno, Czech Republic.
Instituto de Ciencias Aplicadas y Tecnología (ICAT), Universidad Nacional Autónoma de México, Ciudad Universitaria, Ciudad de México 04510, Mexico.
Sensors (Basel). 2020 Mar 6;20(5):1432. doi: 10.3390/s20051432.
Love wave sensors with silver-modified polypyrrole nanoparticles are developed in this work. These systems prove functional at room temperature with enhanced response, sensitivity and response time, as compared to other state-of-the-art surface acoustic wave (SAW) sensors, towards volatile organic compounds (VOCs). Results demonstrate the monitoring of hundreds of ppb of compounds such as acetone, ethanol and toluene with low estimated limits of detection (~3 ppb for acetone). These results are attributed to the use of silver-modified polypyrrole as a second guiding/sensitive layer in the Love wave sensor structure, which provides further chemically active sites for the gas-solid interactions. The sensing of low VOCs concentrations by micro sensing elements as those presented here could be beneficial in future systems for air quality control, food quality control or disease diagnosis via exhaled breath as the limits of detection obtained are within those required in these applications.
本工作开发了具有银修饰聚吡咯纳米粒子的 Love 波传感器。与其他最先进的声表面波(SAW)传感器相比,这些系统在室温下具有增强的响应、灵敏度和响应时间,可用于监测挥发性有机化合物(VOCs)。结果表明,Love 波传感器可监测数百 ppb 的化合物,如丙酮、乙醇和甲苯,其估计的检出限较低(~3 ppb 对丙酮)。这些结果归因于在 Love 波传感器结构中使用银修饰聚吡咯作为第二层引导/敏感层,这为气-固相互作用提供了更多的化学活性位点。由于本文提出的微传感元件可检测低浓度的 VOCs,因此对于未来的空气质量控制、食品质量控制或通过呼气进行疾病诊断的系统可能有益,因为所获得的检出限在这些应用中是必需的。