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基于氨基功能化纳米颗粒的声学传感器用于检测挥发性有机溶剂

Acoustic Sensors Based on Amino-Functionalized Nanoparticles to Detect Volatile Organic Solvents.

作者信息

Matatagui Daniel, Kolokoltsev Oleg, Saniger José Manuel, Gràcia Isabel, Fernández María Jesús, Fontecha Jose Luis, Horrillo María Del Carmen

机构信息

Centro de Ciencias Aplicadas y Dessarrollo Tecnológico (CCADET), UNAM, 04510 Ciudad de Mexico, Mexico.

Instituto de Microelectrónica de Barcelona (IMB), CSIC, Campus UAB, 08193 Bellaterra, Spain.

出版信息

Sensors (Basel). 2017 Nov 14;17(11):2624. doi: 10.3390/s17112624.

Abstract

Love-wave gas sensors based on surface functionalized iron oxide nanoparticles has been developed in this research. Amino-terminated iron oxide nanoparticles were deposited, by a spin coating technique, onto the surface of Love-wave sensors, as a very reproducible gas-sensing layer. The gases tested were organic solvents, such as butanol, isopropanol, toluene and xylene, for a wide and low concentration range, obtaining great responses, fast response times of a few minutes (the time at which the device produced a signal change equal to 90%), good reproducibilities, and different responses for each detected solvent. The estimated limits of detection obtained have been very low for each detected compound, about 1 ppm for butanol, 12 ppm for isopropanol, 3 ppm for toluene and 0.5 ppm for xylene. Therefore, it is demonstrated that this type of acoustic wave sensor, with surface amino-functionalized nanoparticles, is a good alternative to those ones functionalized with metal nanoparticles, which result very expensive sensors to achieve worse results.

摘要

本研究开发了基于表面功能化氧化铁纳米颗粒的洛夫波气体传感器。通过旋涂技术将氨基封端的氧化铁纳米颗粒沉积在洛夫波传感器表面,作为一种具有高度可重复性的气敏层。所测试的气体为有机溶剂,如丁醇、异丙醇、甲苯和二甲苯,浓度范围广且低,获得了良好的响应、几分钟的快速响应时间(设备产生等于90%信号变化的时间)、良好的重现性以及对每种检测到的溶剂的不同响应。对于每种检测到的化合物,所获得的估计检测限非常低,丁醇约为1 ppm,异丙醇为12 ppm,甲苯为3 ppm,二甲苯为0.5 ppm。因此,证明了这种具有表面氨基功能化纳米颗粒的声波传感器是用金属纳米颗粒功能化的传感器的良好替代品,后者是非常昂贵的传感器,且结果更差。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70c6/5712815/6fd71eaad1dd/sensors-17-02624-g001.jpg

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