来自内生菌sp. ECN211的塔拉罗霉素A和B、α-二氢松萝酸酯及曲霉酮B的绝对构型。
Absolute configurations of talaromycones A and B, α-diversonolic ester, and aspergillusone B from endophytic sp. ECN211.
作者信息
Nakashima Ken-Ichi, Tomida Junko, Hirai Takao, Kawamura Yoshiaki, Inoue Makoto
机构信息
Laboratory of Medicinal Resources, School of Pharmacy, Aichi Gakuin University, 1-100 Kusumoto-cho, Chikusa-ku, Nagoya, Aichi, Japan.
Department of Microbiology, School of Pharmacy, Aichi Gakuin University, 1-100 Kusumoto-cho, Chikusa-ku, Nagoya, Aichi, Japan.
出版信息
Beilstein J Org Chem. 2020 Feb 28;16:290-296. doi: 10.3762/bjoc.16.28. eCollection 2020.
Talaromycones A () and B (), new xanthenediones, were isolated from the cultures of sp. ECN211, an endophytic fungus, along with α-diversonolic ester (), aspergillusone B (), glauconic acid (), and rosellisin (). The planar structures of and were elucidated by extensive spectroscopic analyses. Furthermore, the absolute configurations of - were determined by single-crystal X-ray diffraction and electronic circular dichroism spectroscopy (ECD). In addition, the crystallographic data for were updated for the first time in over 50 years.
从内生真菌ECN211菌株的培养物中分离出新型呫吨二酮类化合物塔拉罗米酮A（ ）和B（ ），同时还分离出了α-多样松脂酸酯（ ）、曲霉酮B（ ）、绿胶霉素（ ）和罗塞尔菌素（ ）。通过广泛的光谱分析阐明了 和 的平面结构。此外，通过单晶X射线衍射和电子圆二色光谱（ECD）确定了 - 的绝对构型。此外， 的晶体学数据在50多年来首次得到更新。
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