氢化物转移引发的奥rone 的氧化还原中性级联环化反应：[6,5]螺环的易得途径。
Hydride Transfer Initiated Redox-Neutral Cascade Cyclizations of Aurones: Facile Access to [6,5] Spirocycles.
机构信息
School of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao, 266109, China.
The Affiliated Hospital of Huizhou Health Sciences Polytechnic, Huizhou, 516025, China.
出版信息
Org Lett. 2020 Apr 3;22(7):2537-2541. doi: 10.1021/acs.orglett.0c00309. Epub 2020 Mar 18.
PMID:32186385
Abstract
Reported herein is the hydride transfer initiated redox-neutral cascade cyclizations of aurones, providing a variety of [6,5] spiro-heterocycles in satisfactory yields and good diastereoselectivities.
摘要
本文报道了酮类化合物引发的氢化物转移氧化还原中性级联环化反应，以较高的收率和良好的非对映选择性得到了多种[6,5]螺杂环化合物。
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