通过使用气相阳离子聚合对单晶固态分子有机金属进行表面改性来耐受空气σ-烷烃配合物：SMOM@聚合物
Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation: SMOM@polymer.
作者信息
Bukvic Alexander J, Crivoi Dana Georgiana, Garwood Hollie G, McKay Alasdair I, Chen Thomas T D, Martínez-Martínez Antonio J, Weller Andrew S
机构信息
Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK.
出版信息
Chem Commun (Camb). 2020 Apr 21;56(31):4328-4331. doi: 10.1039/d0cc01140a. Epub 2020 Mar 19.
Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(CyPCHCHPCy)(NBA)][BAr]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.
乙基乙烯基醚的气相表面引发阳离子聚合反应发生在σ-烷烃配合物[Rh(CyPCHCHPCy)(NBA)][BAr]的单晶上。这种新的表面界面使这些通常对空气非常敏感的材料能够耐受空气，同时还允许在晶格内的金属位点上进行单晶到单晶的反应。
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