Abebe Fasil, Sutton Treshaun, Perkins Pierce, Makins-Dennis Khalil, Winstead Angela
Department of Chemistry, Morgan State University, Baltimore, MD, USA.
Green Chem Lett Rev. 2018;11(3):237-245. doi: 10.1080/17518253.2018.1472814. Epub 2018 May 14.
The microwave synthesis of 12 rhodamine-derived imines is described. The present work involves condensation of rhodamine hydrazide with various aromatic aldehydes in ethanol under microwave irradiation. The results obtained indicate that, unlike classical heating, microwave irradiation results in higher yields, shorter reaction time, mild reaction condition and simple work-up procedure. The structures of synthesized compounds were confirmed by H-NMR, C-NMR, FT-IR and high-resolution mass spectra data.
本文描述了12种罗丹明衍生亚胺的微波合成方法。目前的工作涉及在微波辐射下,罗丹明酰肼与各种芳香醛在乙醇中缩合。所得结果表明,与传统加热不同,微波辐射可实现更高的产率、更短的反应时间、温和的反应条件以及简单的后处理程序。通过氢核磁共振(H-NMR)、碳核磁共振(C-NMR)、傅里叶变换红外光谱(FT-IR)和高分辨率质谱数据确认了合成化合物的结构。