Mohseninia Arezou, Kartouzian Dena, Schlumberger Robert, Markötter Henning, Wilhelm Florian, Scholta Joachim, Manke Ingo
Zentrum für Sonnenenergie- und Wasserstoff-Forschung, Baden-Württemberg, Helmholtzstrasse 8, 89081, Ulm, Germany.
AUDI AG, Auto-Union-Straße 1, 85045, Ingolstadt, Germany.
ChemSusChem. 2020 Jun 8;13(11):2931-2934. doi: 10.1002/cssc.202000542. Epub 2020 Apr 30.
An experimental in situ study was performed to investigate the effects of the catalyst layer (CL) and cathode microporous layer (MPL ) perforation on the water management and performance of polymer electrolyte membrane fuel cells (PEMFCs). Polymeric pore formers were utilized to produce perforated CL and MPL structures. High-resolution neutron tomography was employed to visualize the liquid water content and distribution within different components of the cell under channel and land regions. The results revealed that at humid conditions, the perforated layers enhanced the liquid water transport under the channel regions. Moreover, at high current densities, the performance was improved for the cells with perforated layers compared to a baseline cell with non-perforated layers, owing to reduced mass transport losses.
进行了一项实验性原位研究,以探究催化剂层(CL)和阴极微孔层(MPL)穿孔对聚合物电解质膜燃料电池(PEMFC)水管理和性能的影响。利用聚合物致孔剂来制备穿孔的CL和MPL结构。采用高分辨率中子断层扫描技术来可视化电池不同组件在流道和脊区域下的液态水含量及分布。结果表明,在潮湿条件下,穿孔层增强了流道区域下的液态水传输。此外,在高电流密度下,与无穿孔层的基线电池相比,有穿孔层的电池性能得到了改善,这是由于传质损失降低所致。