Czop Monika, Łaźniewska-Piekarczyk Beata
Department of Technologies and Installations for Waste Management, Faculty of Energy and Environmental Engineering, The Silesian University of Technology, Konarskiego 18, 44-100 Gliwice, Poland.
Department of Building Engineering and Building Physics, Faculty of Civil Engineering, The Silesian University of Technology, Akademicka 5, 44-100 Gliwice, Poland.
Materials (Basel). 2020 Mar 31;13(7):1593. doi: 10.3390/ma13071593.
In Europe, the use of wastes in the cement and construction industry follows the assumptions of sustainability and the idea of circular economy. At present, it is observed that cement plants introduce wastes to the cement in the form of so-called mineral additives. The most often used mineral additives are: fly ash with silica fume, granulated blast furnace slag and silica fume. The use of mineral additives in the cement is related to the fact that the use of the most expensive component of cement-Portland cement clinker-is limited. The purpose of the article is a preliminary evaluation of the suitability of slag from the municipal solid waste incineration plant for its use as a replacement of cement. In this article, slag from the municipal solid waste incineration (MSWI) replaces cement in the quantity of 30%, and presents the content of oxides and elements of slag from the MSWI. The obtained results are compared to the requirements that the crushed and granulated blast furnace slag need to meet to be suitable for use as an additive of type II to the concrete. The conducted analyses confirmed that the tested slag meets the requirements for the granulated blast furnace slag as an additive to the concrete in the following parameters: CaO ≤ 18.0%, SO3 ≤ 2.5% and Cl ≤ 0.1%. At the same time, mechanical features were tested of the designed mortars which consisted of a mixture of Portland cement (CEM I) with 30% of slag admixture. The designed mortar after 28 days of maturing reached a compressive strength of 32.0 MPa, and bending strength of 4.0 MPa. When compared to the milled granulated blast furnace slag (GBFS), the obtained values are slightly lower. Furthermore, the hardened mortars were subject to a leachability test to check the impact on the environment. Test results showed that the aqueous extracts from mixtures with 30% of slag admixtures slightly exceed the limits and do not pose a sufficiant threat to the environment as to eliminate the MSWI slag from economical use.
在欧洲,水泥和建筑业对废弃物的利用遵循可持续发展的理念以及循环经济的思想。目前,可以观察到水泥厂以所谓矿物添加剂的形式将废弃物引入水泥中。最常用的矿物添加剂有:粉煤灰与硅灰、粒化高炉矿渣和硅灰。在水泥中使用矿物添加剂与水泥最昂贵的成分——波特兰水泥熟料的使用受限这一事实有关。本文的目的是对城市固体废物焚烧厂的矿渣用作水泥替代品的适用性进行初步评估。在本文中,城市固体废物焚烧(MSWI)产生的矿渣以30%的量替代水泥,并呈现了MSWI矿渣的氧化物和元素含量。将所得结果与碎粒化高炉矿渣用作混凝土II型添加剂所需满足的要求进行比较。所进行的分析证实,测试的矿渣在以下参数方面满足作为混凝土添加剂的粒化高炉矿渣的要求:CaO≤18.0%,SO3≤2.5%,Cl≤0.1%。同时,对由波特兰水泥(CEM I)与30%矿渣掺合料的混合物组成的设计砂浆进行了力学性能测试。设计的砂浆在养护28天后达到了32.0MPa的抗压强度和4.0MPa的抗弯强度。与磨细粒化高炉矿渣(GBFS)相比,所得值略低。此外,对硬化砂浆进行了浸出性测试以检查其对环境的影响。测试结果表明,含有30%矿渣掺合料的混合物的水提取物略超出限值,但对环境不构成足以排除MSWI矿渣经济利用的威胁。