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用于合成（）-链烯基硼酸频哪醇酯的光谱数据 炔烃的硼氢化反应。 需注意，原文括号部分内容缺失，翻译可能会不太准确。

Spectral data for the synthesis of ()-alkenylboronic acid pinacol esters hydroboration of alkynes.

作者信息

Gioia Bruna, Arnaud Alexandre, Radix Sylvie, Walchshofer Nadia, Doléans-Jordheim Anne, Rocheblave Luc

机构信息

Univ Lyon, Université Claude Bernard Lyon 1, ISPB-Faculté de Pharmacie, EA 4446, B2MC, F-69373, Lyon Cedex 08, France.

Univ Lyon, Université Claude Bernard Lyon 1, VetAgro Sup, UMR CNRS 5557, Ecologie Microbienne, F-69622, Villeurbanne, France.

出版信息

Data Brief. 2020 Mar 3;30:105354. doi: 10.1016/j.dib.2020.105354. eCollection 2020 Jun.

DOI:10.1016/j.dib.2020.105354
PMID:32258264
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7109635/
Abstract

This data article is related to a research paper entitled "Solvent- and metal-free hydroboration of alkynes under microwave irradiation" (Gioia et al. TETL-D-19-01698) [1]. Herein we present the spectral data acquired from the synthesis of ()-alkenyl boronic acid pinacol esters. The data include the general information and the synthetic procedure affording the target derivatives, which were fully characterized by Nuclear Magnetic Resonance (H and C NMR) and, for the most part, by Electrospray Ionization High Resolution Mass (ESI-MS). Proton and carbon NMR spectra and ESI-MS spectra were provided which will be useful for further organic chemists if they are interested in the synthesis of these building blocks.

摘要

本数据文章与一篇题为《微波辐射下炔烃的无溶剂无金属硼氢化反应》（乔亚等人，TETL-D-19-01698）[1]的研究论文相关。在此，我们展示了从（）-烯基硼酸频哪醇酯合成过程中获取的光谱数据。这些数据包括目标衍生物的一般信息和合成步骤，通过核磁共振（氢和碳核磁共振）对其进行了全面表征，并且大部分通过电喷雾电离高分辨率质谱（ESI-MS）进行了表征。提供了质子和碳核磁共振光谱以及ESI-MS光谱，若有机化学家对这些结构单元的合成感兴趣，这些光谱将对他们有所帮助。

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Org Lett. 2019 Jan 4;21(1):142-146. doi: 10.1021/acs.orglett.8b03599. Epub 2018 Dec 20.
2
Lewis acid catalysis: regioselective hydroboration of alkynes and alkenes promoted by scandium triflate.路易斯酸催化：三氟甲磺酸钪促进的炔烃和烯烃的区域选择性硼氢化反应。
Chem Commun (Camb). 2018 Dec 4;54(97):13690-13693. doi: 10.1039/c8cc08361d.
3
Electrophilic Borylation of Terminal Alkenes with BBr/2,6-Disubstituted Pyridines.
硼原子亲电试剂对末端烯烃的硼化反应（BBr/2,6-取代吡啶）。
Org Lett. 2018 Apr 6;20(7):1828-1831. doi: 10.1021/acs.orglett.8b00335. Epub 2018 Mar 12.
4
Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents.双（烯基）硼酸酯的对映选择性联合交叉偶联：手性烯丙基硼试剂的通用合成方法
J Am Chem Soc. 2017 Apr 12;139(14):5027-5030. doi: 10.1021/jacs.7b01774. Epub 2017 Mar 29.
5
Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane.路易斯酸催化：由皮尔斯硼烷引发的炔烃催化硼氢化反应。
Chem Commun (Camb). 2016 Sep 18;52(72):10830-3. doi: 10.1039/c6cc05360b. Epub 2016 Jul 18.
6
Pd-Catalyzed Hydroborylation of Alkynes: A Ligand Controlled Regioselectivity Switch for the Synthesis of α- or β-Vinylboronates.钯催化的炔烃硼氢化反应：用于合成α-或β-乙烯基硼酸酯的配体控制区域选择性开关
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7
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Org Lett. 2014 Sep 5;16(17):4670-3. doi: 10.1021/ol502285s. Epub 2014 Aug 25.
8
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Chem Commun (Camb). 2014 Feb 25;50(16):2058-60. doi: 10.1039/c3cc48670b.