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韩国各种食品中的短链氯化石蜡:含量、同系物分布及人体膳食暴露情况。

Short-chain chlorinated paraffins in various foods from Republic of Korea: Levels, congener patterns, and human dietary exposure.

机构信息

Department of Civil and Environmental Engineering, Pusan National University, Busan, 46241, Republic of Korea.

School of Environmental Science and Engineering, Pohang University of Science and Technology, Cheongam-ro 77, Nam-gu, Pohang, Kyungbuk, 790-784, Republic of Korea.

出版信息

Environ Pollut. 2020 Aug;263(Pt B):114520. doi: 10.1016/j.envpol.2020.114520. Epub 2020 Apr 4.

Abstract

Short-chain chlorinated paraffin (SCCP) concentrations in 419 food samples (from 59 species) from Republic of Korea were determined. The SCCP concentrations and lipid contents in whole foods positively correlated and the highest SCCP concentration (891 ng/g wet weight) was observed in fats and oils. The SCCP concentrations were higher in benthic fish/shellfish and demersal fish than other fish and shellfish. The SCCP concentrations were higher in duck meat and eggs than meat and eggs of other species. The chlorine-based congener group patterns were related to the lipid contents of the foods. SCCPs in eggs (high lipid content) were dominated by more-chlorinated SCCPs (particularly Cl-SCCPs, which contributed 43% of the total) but SCCPs in seaweed (low lipid content) were dominated by less-chlorinated SCCPs (particularly Cl-SCCPs, which contributed 46%). Dietary SCCP intakes were calculated using the median SCCP concentrations and estimated 888 and 781 ng/kg/d for male and female Korean adults, respectively. The predominant contributing foods to SCCP dietary exposure differed according to sex and age. Dairy products contributed most (about 50%) for infants/children (1-5 y old), but meat and dairy products contributed most for adult males and females, respectively. Grain contributed most for ≥65 y old.

摘要

测定了来自韩国的 419 种食品(来自 59 个物种)中的短链氯化石蜡 (SCCP) 浓度。全食品中的 SCCP 浓度与脂质含量呈正相关,脂肪和油中的 SCCP 浓度最高(891ng/g 湿重)。底栖鱼类/贝类和底层鱼类中的 SCCP 浓度高于其他鱼类和贝类。鸭肉和蛋类中的 SCCP 浓度高于其他物种的肉类和蛋类。基于氯的同系物组模式与食品的脂质含量有关。(脂质含量高的)蛋类中的 SCCPs 以高氯代 SCCPs 为主(尤其是 Cl-SCCPs,占总 SCCPs 的 43%),而(脂质含量低的)海藻中的 SCCPs 则以低氯代 SCCPs 为主(尤其是 Cl-SCCPs,占总 SCCPs 的 46%)。使用中位数 SCCP 浓度和估计的 SCCP 浓度计算膳食 SCCP 摄入量,分别为韩国男性和女性成年人 888 和 781ng/kg/d。根据性别和年龄的不同,SCCP 膳食暴露的主要贡献食品也有所不同。对于 1-5 岁的婴幼儿,乳制品的贡献最大(约占 50%),但肉类和乳制品对成年男性和女性的贡献最大,而谷物对≥65 岁的人贡献最大。

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