Chen Yian, Pötschke Petra, Pionteck Jürgen, Voit Brigitte, Qi Haisong
Leibniz-Institut für Polymerforschung Dresden e.V. (Leibniz Institute of Polymer Research Dresden), Hohe Straße 6, 01069 Dresden, Germany.
Organic Chemistry of Polymers, Technische Universität Dresden, 01062 Dresden, Germany.
ACS Appl Mater Interfaces. 2020 May 13;12(19):22088-22098. doi: 10.1021/acsami.9b23052. Epub 2020 Apr 29.
Cellulose/reduced graphene oxide (rGO)/FeO aerogels exhibiting strong electromagnetic wave absorption were prepared by a green, simple, and scalable coprecipitation process. With rGO loading of 8 wt % and FeO content of approx. 15 wt %, the electromagnetic interference shielding effectiveness (EMI SE) of the cellulose/rGO/FeO aerogel with 0.5 mm thickness reached 32.4-40.1 dB at 8.2-12.4 GHz. The EMI shielding performance of cellulose/rGO/FeO aerogels was higher for larger rGO loading (varied between 3 and 8 wt %) and greatly improved on increasing the sample thickness (varied between 0.5 and 2 mm). At 2.0 mm thickness, SE values of 49.4-52.4 dB were reached. Absorption plays a major role in the EMI shielding mechanism of cellulose/rGO/FeO aerogels. The multireflection of microwaves and impedance matching provides the highly efficient EMI shielding caused by the combined effects of the porous structure, rGO sheets, and FeO nanoparticles. The results demonstrate that these lightweight aerogels are suitable for EMI shielding.
通过绿色、简单且可扩展的共沉淀法制备了具有强电磁波吸收性能的纤维素/还原氧化石墨烯(rGO)/FeO气凝胶。当rGO负载量为8 wt%且FeO含量约为15 wt%时,厚度为0.5 mm的纤维素/rGO/FeO气凝胶在8.2 - 12.4 GHz频段的电磁干扰屏蔽效能(EMI SE)达到32.4 - 40.1 dB。对于较大的rGO负载量(在3至8 wt%之间变化),纤维素/rGO/FeO气凝胶的EMI屏蔽性能更高,并且随着样品厚度增加(在0.5至2 mm之间变化)而显著提高。在厚度为2.0 mm时,SE值达到49.4 - 52.4 dB。吸收在纤维素/rGO/FeO气凝胶的EMI屏蔽机制中起主要作用。微波的多次反射和阻抗匹配提供了由多孔结构、rGO片层和FeO纳米颗粒的综合作用引起的高效EMI屏蔽。结果表明,这些轻质气凝胶适用于EMI屏蔽。