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公园游乐场重金属的生态风险评价与来源解析:以中国西北城市陕西省西安市为例。

Ecological risk evaluation and source apportionment of heavy metals in park playgrounds: a case study in Xi'an, Shaanxi Province, a northwest city of China.

机构信息

College of Geomatics, Xi'an University of Science and Technology, Xi'an, China.

School of Public Health, Xi'an Jiaotong University, Xi'an, China.

出版信息

Environ Sci Pollut Res Int. 2020 Jul;27(19):24400-24412. doi: 10.1007/s11356-020-08744-x. Epub 2020 Apr 18.

DOI:10.1007/s11356-020-08744-x
PMID:32306261
Abstract

Park playgrounds recently are suffering serious heavy metals contamination in China. It is urgent to assess the ecological risk and identify the sources for heavy metals. A total of 111 topsoil samples were collected from four park playgrounds in Xi'an, and the X-ray fluorescence (XRF) instrument was used to measure the concentrations of heavy metals including chromium(Cr), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), lead (Pb), manganese (Mn), and cobalt (Co), respectively. Ecological risk ([Formula: see text]) and potential ecological risk index (RI) were introduced to determine the pollution level and ecological risk, and the absolute principal component score-multiple linear regression (APCS-MLR) model was implemented to identify the sources for heavy metals. The main results were as follows. (1) Except As, the mean concentrations of measured heavy metals of four park playgrounds surpassed the soil background values of Shaanxi Province. (2) In each park playground, the [Formula: see text] was below a "low" risk level ([Formula: see text]=10) for Cr, Ni, Zn, As, and Mn; Cu was between a "moderate" and "considerable" risk level; Pb was between a "low" and "moderate" risk level; and [Formula: see text] was between a "considerable" and "high" risk level for Co. Besides, the RI index was on a "high" risk level (120 < RI < 240) with an obvious spatial distinction. (3) The anthropogenic factors were the main sources for heavy metals, and mixed sources and natural sources were considered as the minor sources for metals. (4) The sources contributions for Co had obvious spatial heterogeneity in each park situated in four different urban planning districts.

摘要

中国的公园游乐场最近遭受了严重的重金属污染。评估重金属的生态风险并确定其来源迫在眉睫。本研究共采集了西安四个公园游乐场的 111 个表层土壤样本,使用 X 射线荧光(XRF)仪器分别测定铬(Cr)、镍(Ni)、铜(Cu)、锌(Zn)、砷(As)、铅(Pb)、锰(Mn)和钴(Co)等重金属的浓度。引入生态风险([Formula: see text])和潜在生态风险指数(RI)来确定污染水平和生态风险,并采用绝对主成分得分-多元线性回归(APCS-MLR)模型来识别重金属的来源。主要结果如下:(1)除 As 外,四个公园游乐场的重金属实测均值均超过陕西省土壤背景值。(2)在每个公园游乐场中,Cr、Ni、Zn、As 和 Mn 的[Formula: see text]均处于低风险水平([Formula: see text]=10);Cu 处于中-高风险水平;Pb 处于低-中风险水平;Co 处于中-高风险水平;此外,RI 指数处于高风险水平(120<RI<240),且具有明显的空间差异。(3)人为因素是重金属的主要来源,混合来源和自然来源被认为是金属的次要来源。(4)在位于四个不同城市规划区的四个公园中,Co 的来源贡献具有明显的空间异质性。

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