铜催化的C(sp)-Si和C(sp)-B键形成的最新进展。
Recent advances in Cu-catalyzed C(sp)-Si and C(sp)-B bond formation.
作者信息
Takale Balaram S, Thakore Ruchita R, Etemadi-Davan Elham, Lipshutz Bruce H
机构信息
Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, USA.
出版信息
Beilstein J Org Chem. 2020 Apr 15;16:691-737. doi: 10.3762/bjoc.16.67. eCollection 2020.
Numerous reactions generating C-Si and C-B bonds are in focus owing to the importance of incorporating silicon or boron into new or existing drugs, in addition to their use as building blocks in cross-coupling reactions en route to various targets of both natural and unnatural origins. In this review, recent protocols relying on copper-catalyzed sp carbon-silicon and carbon-boron bond-forming reactions are discussed.
由于将硅或硼纳入新的或现有的药物中具有重要意义，以及它们在通向各种天然和非天然来源目标的交叉偶联反应中作为构建单元的用途，众多生成碳 - 硅键和碳 - 硼键的反应受到关注。在本综述中，将讨论依赖铜催化的sp碳 - 硅和碳 - 硼键形成反应的最新方法。
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