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还原氧化石墨烯气凝胶的制备及其对Pb(II)的吸附

Preparation of Reduced Graphene Oxide Aerogel and Its Adsorption for Pb(II).

作者信息

Gao Chunjuan, Dong Zeliang, Hao Xiaocui, Yao Ying, Guo Shuyuan

机构信息

Institute of Seawater Desalination and Multipurpose Utilization, MNR(Tianjin), Tianjin 300192, P. R. China.

出版信息

ACS Omega. 2020 Apr 24;5(17):9903-9911. doi: 10.1021/acsomega.0c00183. eCollection 2020 May 5.

Abstract

In this study, reduced graphene oxide (rGO) aerogels were successfully prepared using a facile hydrothermal method and determined with Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller surface area, and scanning electron microscopy. The rGO aerogels were used to remove Pb(II) from aqueous solution, and the adsorption performance of rGO aerogels was investigated. In addition, the adsorption-desorption cycle experiments were carried out to evaluate the recyclability and stability of rGO aerogels. The adsorption data were consistent with the pseudo-second-order kinetic model and Langmuir isotherm model. The experimental results showed that rGO aerogels have good adsorption capacity for Pb(II) and can be utilized for wastewater treatment.

摘要

在本研究中,采用简便的水热法成功制备了还原氧化石墨烯(rGO)气凝胶,并通过傅里叶变换红外光谱、X射线衍射光谱、拉曼光谱、X射线光电子能谱、布鲁诺尔-埃米特-泰勒比表面积和扫描电子显微镜对其进行了表征。将rGO气凝胶用于从水溶液中去除Pb(II),并研究了rGO气凝胶的吸附性能。此外,进行了吸附-解吸循环实验以评估rGO气凝胶的可回收性和稳定性。吸附数据符合准二级动力学模型和朗缪尔等温线模型。实验结果表明,rGO气凝胶对Pb(II)具有良好的吸附能力,可用于废水处理。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/007d/7203952/343cb11fd080/ao0c00183_0001.jpg

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