On the adsorption kinetics and mechanism of enhanced photocatalytic activity of Fe O -SiO -TiO core-multishell nanoparticles against E. coli.

In the present study, a Fe O -TiO (FT) core-shell and a core-multishell structure of Fe O -SiO -TiO (FST) were synthesized, and their bactericidal capability was investigated on Escherichia coli (E. coli). Scanning electron microscopy (SEM), ultraviolet-visible spectroscopy (UV-vis), X-ray diffraction, Brunauer-Emmett-Teller, zeta potential, and fluorimetry were carried out to characterize properties of synthesized nanoparticles. An efficiency of 98% adsorption and harsh bacterial damage was observed when E. coli was put in contact with FST. Weaker adsorption of bacteria in contact with FT demonstrated that heterojunction has destructive effects on nanostructure. Further investigation proved that more OH were produced on the surface of FST, which is a sign of its longer lifetime. Moreover, results revealed that the presence of SiO in the structure caused enhanced coverage, surface area, and porosity in TiO outer layer, all of which have positive effects on adsorption. However, UV-vis showed smaller band gap for FT. It suggests that although photoactivity of FST is less influenced by light absorption, it possesses more e/h lifetime for generation of reactive oxygen species. Results point to the importance of SiO as an obstacle of heterojunction on both adsorption and photoactivity. It was also proposed that increasing band gap in FST can be attributed to the porosity of SiO that causes suppression of TiO nanocrystallite growth.