Department of Pharmacy, Schoo of Chemical Engineering, Dalian University of Technology, No. 2 Linggong Road, Dalian 116024, China.
Chem Commun (Camb). 2020 Jul 7;56(53):7333-7336. doi: 10.1039/d0cc02921a. Epub 2020 Jun 2.
Zinc(ii)-catalyzed intramolecular hydroarylation-redox cross-dehydrogenative coupling of N-propargylanilines with two types of carbon pronucleophiles (nitromethane as a sp carbon pronucleophile and phenylacetylenes as sp carbon pronucleophiles) proceeded to give the 2-substituted tetrahydroquinolines in good yields with 100% atomic utilization without any additional external oxidants.
锌(ii)催化的 N-炔丙基苯胺与两种类型的碳亲核试剂（硝基甲烷作为 sp 碳亲核试剂和苯乙炔作为 sp 碳亲核试剂）的分子内氢芳基化-氧化交叉脱氢偶联反应以高收率得到 2-取代的四氢喹啉，原子利用率为 100%，无需任何额外的外部氧化剂。
