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直接沉积 GC/IR 技术在天然产物鉴定中的应用。

Direct deposition GC/IR techniques in natural product identification.

机构信息

Institut für Organische Chemie, TU Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.

出版信息

Nat Prod Rep. 2020 Dec 16;37(12):1561-1567. doi: 10.1039/d0np00013b.

DOI:10.1039/d0np00013b
PMID:32490464
Abstract

Covering: up to the end of 2019 The application of coupled gas chromatography/direct deposition Fourier transform infrared (GC/DD-FTIR) spectroscopy in the field of volatile natural product identification yields orthogonal information to GC/MS analysis about functional groups and C-C double bonds. This underused method facilitates structure elucidation of trace compounds and can be combined with modern DFT-calculation to further improve the usefulness of the obtained results.

摘要

涵盖

截至 2019 年底 耦合气相色谱/直接沉积傅里叶变换红外(GC/DD-FTIR)光谱在挥发性天然产物鉴定领域的应用提供了关于官能团和 C-C 双键的与 GC/MS 分析正交的信息。这种未充分利用的方法有助于痕量化合物的结构阐明,并且可以与现代 DFT 计算相结合,以进一步提高所获得结果的有用性。

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