Masłowski Marcin, Miedzianowska Justyna, Czylkowska Agnieszka, Strzelec Krzysztof
Institute of Polymer & Dye Technology, Lodz University of Technology, Stefanowskiego 12/16, 90-924 Lodz, Poland.
Institute of General and Ecological Chemistry, Lodz University of Technology, Żeromskiego 116, 90-924 Lodz, Poland.
Materials (Basel). 2020 Jun 2;13(11):2526. doi: 10.3390/ma13112526.
Over the past decades, increased scientific and research activity has been observed in the development of new, innovative materials for various end uses. This is mainly due to the growing ecological, environmental, and material awareness of many industries and societies. -horsetail is a plant that has demonstrated its properties in pharmacological and clinical aspects as well as in vitro and in vivo biological activity. This article presents a new method of using horsetail as a natural, lignocellulosic filler for a natural rubber matrix. In-depth characteristics of the applied bio-additive were prepared based on several research techniques and methods such as ultraviolet-visible spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy with energy dispersive X-RAY spectroscopy, thermogravimetric analysis, and flame atomic absorption spectroscopy. Elastomer composites were prepared as a function of horsetail content. Then, an analysis of their main functional properties was performed, including mechanical properties and susceptibility to accelerated aging processes such as thermo-oxidative, ultraviolet radiation, and weathering. The research emphasizes the significant value of horsetail in its new role-as an active filler of elastomer biocomposites. The obtained results confirmed that horsetail is lignocellulosic material thermally stable up to 180 °C. Horsetail is an active filler to natural rubber, positively affecting mechanical strength. Due to the presence of flavonoids and phenolic acids in horsetail, it can be used as a polymer anti-aging agent.
在过去几十年中,人们观察到在开发用于各种最终用途的新型创新材料方面,科学和研究活动有所增加。这主要是由于许多行业和社会对生态、环境和材料的认识不断提高。问荆是一种在药理学和临床方面以及体外和体内生物活性方面都已展现其特性的植物。本文介绍了一种将问荆用作天然橡胶基质的天然木质纤维素填料的新方法。基于紫外可见光谱、傅里叶变换红外光谱、带有能量色散X射线光谱的扫描电子显微镜、热重分析和火焰原子吸收光谱等多种研究技术和方法,对所应用的生物添加剂进行了深入表征。根据问荆含量制备了弹性体复合材料。然后,对其主要功能特性进行了分析,包括机械性能以及对热氧化、紫外线辐射和耐候性等加速老化过程的敏感性。该研究强调了问荆在其新角色——作为弹性体生物复合材料的活性填料——中的重要价值。所得结果证实,问荆是一种热稳定性高达180°C的木质纤维素材料。问荆是天然橡胶的活性填料,对机械强度有积极影响。由于问荆中存在黄酮类化合物和酚酸,它可用作聚合物抗老化剂。