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对热水解预处理和厌氧消化产生的A级生物固体进行的全面研究。

Full scale study of Class A biosolids produced by thermal hydrolysis pretreatment and anaerobic digestion.

作者信息

Wang Xuanzhao, Andrade Natasha, Shekarchi Jessica, Fischer Sarah J, Torrents Alba, Ramirez Mark

机构信息

Department of Civil and Environmental Engineering, University of Maryland, College Park, MD 20742, USA.

Department of Civil and Environmental Engineering, University of Maryland, College Park, MD 20742, USA.

出版信息

Waste Manag. 2018 Aug;78:43-50. doi: 10.1016/j.wasman.2018.05.026. Epub 2018 May 21.

Abstract

Biosolids are the solid by-product of wastewater treatment and contain high-organic matter and nutrient content, which can be utilized in food production and gardening. In 2014, this study's target nutrient recovery facility (NRF) in the Mid-Atlantic region of the U.S. adopted thermal hydrolysis pretreatment (THP) and anaerobic digestion (AD) to upgrade biosolids from Class B (lime-stabilized) to Class A. The pathogen, nutrients, and metals contents were compared with that of Class B biosolids from the same facility throughout a one-year period. Following optimization and equilibrium, stable biosolids were produced that satisfied all Environmental Protection Agency (EPA) Class A biosolids standards. Class A biosolids produced had fecal coliform density consistently below the 1000 MPN/g d.w. limit set by the EPA, at 35.85 ± 81.10 MPN/g d.w. (n = 301). Metal concentrations were greater in Class A than Class B biosolids as a result of biosolids mass reduction, but these levels were substantially lower than regulatory limits. Metal concentrations were (in mg/kg d.w.): As = 6.43 ± 0.400 (n = 141), Cd = 3.39 ± 0.117 (n = 147), Cr = 88.4 ± 2.00 (n = 148), Cu = 401 ± 9.81 (n = 148), Pb = 68.1 ± 2.19 (n = 148), Hg = 1.21 ± 0.116 (n = 148), Mo = 14.9 ± 0.321 (n = 148), Ni = 23.8 ± 0.911 (n = 146), Se = 10.0 ± 0.573 (n = 140), Zn = 778 ± 14.9 (n = 148), K = 850 ± 21.7 (n = 134). In addition, Class A biosolids were rich in total nitrogen (N) and higher in total phosphorus (TP), but low in potassium (K) content. Concentration of K was 850 ± 21.7 mg/kg d.w. (n = 134), TKN was 52,000 ± 13,300 mg/kg d.w. (n = 43), TP was 34,500 ± 6130 mg/kg d.w. (n = 42), and ammonia-N was 7860 ± 1350 mg/kg d.w. (n = 43).

摘要

生物固体是废水处理产生的固体副产品,含有高有机质和营养成分,可用于食品生产和园艺。2014年,美国中大西洋地区本研究的目标营养物回收设施(NRF)采用热水解预处理(THP)和厌氧消化(AD)将B级(石灰稳定)生物固体升级为A级。在一年的时间里,将病原体、营养物和金属含量与同一设施的B级生物固体进行了比较。经过优化和平衡,生产出了符合美国环境保护局(EPA)所有A级生物固体标准的稳定生物固体。所生产的A级生物固体的粪大肠菌群密度始终低于EPA设定的1000 MPN/g干重限值,为35.85±81.10 MPN/g干重(n = 301)。由于生物固体质量减少,A级生物固体中的金属浓度高于B级,但这些水平远低于监管限值。金属浓度(以mg/kg干重计)为:砷=6.43±0.400(n = 141),镉=3.39±0.117(n = 147),铬=88.4±2.00(n = 148),铜=401±9.81(n = 148),铅=68.1±2.19(n = 148),汞=1.21±0.116(n = 148),钼=14.9±0.321(n = 148),镍=23.8±0.911(n = 146),硒=10.0±0.573(n = 140),锌=778±14.9(n = 148),钾=850±21.7(n = 134)。此外,A级生物固体总氮(N)含量丰富,总磷(TP)含量较高,但钾(K)含量较低。钾的浓度为850±21.7 mg/kg干重(n = 134),总凯氏氮为52,000±13,300 mg/kg干重(n = 43),总磷为34,500±6130 mg/kg干重(n = 42),氨氮为7860±1350 mg/kg干重(n = 43)。

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