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从报废电子废物中回收稀土元素 (REEs) 的新兴技术:进展、挑战和展望综述。

Emerging technologies for the recovery of rare earth elements (REEs) from the end-of-life electronic wastes: a review on progress, challenges, and perspectives.

机构信息

Department of Civil, Environmental, Architectural Engineering and Mathematics, University of Brescia, Via Branze 43, 25123, Brescia, Italy.

Department of chemistry, Mekelle University, Mekelle, Ethiopia.

出版信息

Environ Sci Pollut Res Int. 2020 Oct;27(29):36052-36074. doi: 10.1007/s11356-020-09630-2. Epub 2020 Jul 2.

Abstract

The demand for rare earth elements (REEs) has significantly increased due to their indispensable uses in integrated circuits of modern technology. However, due to the extensive use of high-tech applications in our daily life and the depletion of their primary ores, REE's recovery from secondary sources is today needed. REEs have now attracted attention to policymakers and scientists to develop novel recovery technologies for materials' supply sustainability. This paper summarizes the recent progress for the recovery of REEs using various emerging technologies such as bioleaching, biosorption, cryo-milling, electrochemical processes and nanomaterials, siderophores, hydrometallurgy, pyrometallurgy, and supercritical CO. The challenges facing this recovery are discussed comprehensively and some possible improvements are presented. This work also highlights the economic and engineering aspects of the recovery of REE from waste electrical and electronic equipment (WEEE). Finally, this review suggests that greener and low chemical consuming technologies, such as siderophores and electrochemical processes, are promising for the recovery of REEs present in small quantities. These technologies present also a potential for large-scale application.

摘要

由于稀土元素 (REEs) 在现代技术集成电路中不可或缺的用途,对其的需求显著增加。然而,由于高 科技 在日常生活中的广泛应用以及主要矿石的枯竭,如今需要从二次资源中回收 REE。 REE 已经引起了政策制定者和科学家的关注,他们正在开发新的回收技术,以确保材料供应的可持续性。本文总结了使用各种新兴技术(如生物浸出、生物吸附、冷冻粉碎、电化学过程和纳米材料、铁载体、湿法冶金、火法冶金和超临界 CO )回收 REE 的最新进展。全面讨论了回收过程中面临的挑战,并提出了一些可能的改进措施。这项工作还突出了从废弃电子电气设备 (WEEE) 中回收 REE 的经济和工程方面。最后,本综述表明,对于从少量存在的 REE 中回收,使用铁载体和电化学过程等更环保和低化学消耗的技术具有很大的前景。这些技术也具有大规模应用的潜力。

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