氮氧化物介导聚合反应的新变体
New Variants of Nitroxide Mediated Polymerization.
作者信息
Audran Gérard, Bagryanskaya Elena G, Marque Sylvain R A, Postnikov Pavel
机构信息
Aix Marseille Univ, CNRS, ICR, UMR 7273, Case 551, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France.
N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry Siberian Branch of Russian Academy of Sciences, Pr. Lavrentjeva 9, Novosibirsk 630090, Russia.
出版信息
Polymers (Basel). 2020 Jul 2;12(7):1481. doi: 10.3390/polym12071481.
Nitroxide-mediated polymerization is now a mature technique, at 35 years of age. During this time, several variants have been developed: electron spin capture polymerization (ESCP), photoNMP (NMP2), chemically initiated NMP (CI-NMP), spin label NMP (SL-NMP), and plasmon-initiated NMP (PI-NMP). This mini-review is devoted to the features and applications of these variants.
氮氧化物介导的聚合反应如今已是一项成熟的技术，至今已有35年历史。在此期间，已开发出多种变体：电子自旋捕获聚合反应（ESCP）、光氮氧介导的聚合反应（NMP2）、化学引发的氮氧介导的聚合反应（CI-NMP）、自旋标记氮氧介导的聚合反应（SL-NMP）以及等离子体引发的氮氧介导的聚合反应（PI-NMP）。本综述将专注于这些变体的特点及应用。
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