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聚丁二酸丁二醇酯(PBS)/淀粉/甘油复合板材中空果串(EFB)纤维增强的表征研究

Characterization Study of Empty Fruit Bunch (EFB) Fibers Reinforcement in Poly(Butylene) Succinate (PBS)/Starch/Glycerol Composite Sheet.

作者信息

Ayu Rafiqah S, Khalina Abdan, Harmaen Ahmad Saffian, Zaman Khairul, Isma Tawakkal, Liu Qiuyun, Ilyas R A, Lee Ching Hao

机构信息

Laboratory of Biocomposite Technology, INTROP, Universiti Putra Malaysia, Serdang 43400, Selangor, Malaysia.

Engineering Faculty, UPM, Serdang 43400, Selangor, Malaysia.

出版信息

Polymers (Basel). 2020 Jul 15;12(7):1571. doi: 10.3390/polym12071571.

Abstract

In this study, a mixture of thermoplastic polybutylene succinate (PBS), tapioca starch, glycerol and empty fruit bunch fiber was prepared by a melt compounding method using an industrial extruder. Generally, insertion of starch/glycerol has provided better strength performance, but worse thermal and water uptake to all specimens. The effect of fiber loading on mechanical, morphological, thermal and physical properties was studied in focus. Low interfacial bonding between fiber and matrix revealed a poor mechanical performance. However, higher fiber loadings have improved the strength values. This is because fibers regulate good load transfer mechanisms, as confirmed from SEM micrographs. Tensile and flexural strengths have increased 6.0% and 12.2%, respectively, for 20 wt% empty fruit bunch (EFB) fiber reinforcements. There was a slightly higher mass loss for early stage thermal decomposition, whereas regardless of EFB contents, insignificant changes on decomposition temperature were recorded. A higher lignin constituent in the composite (for high natural fiber volume) resulted in a higher mass residue, which would turn into char at high temperature. This observation indirectly proves the dimensional integrity of the composite. However, as expected, with higher EFB fiber contents in the composite, higher values in both the moisture uptake and moisture loss analyses were found. The hydroxyl groups in the EFB absorbed water moisture through formation of hydrogen bonding.

摘要

在本研究中,采用工业挤出机通过熔融共混法制备了热塑性聚丁二酸丁二醇酯(PBS)、木薯淀粉、甘油和空果串纤维的混合物。一般来说,淀粉/甘油的加入使所有试样的强度性能有所提高,但热性能和吸水性变差。重点研究了纤维含量对机械、形态、热和物理性能的影响。纤维与基体之间的低界面结合导致力学性能较差。然而,较高的纤维含量提高了强度值。这是因为纤维调节了良好的载荷传递机制,扫描电子显微镜照片证实了这一点。对于20 wt%的空果串(EFB)纤维增强材料,拉伸强度和弯曲强度分别提高了6.0%和12.2%。在热分解早期有稍高的质量损失,而无论EFB含量如何,分解温度的变化都不显著。复合材料中较高的木质素成分(对于高天然纤维体积)导致较高的质量残留,在高温下会变成焦炭。这一观察结果间接证明了复合材料的尺寸完整性。然而,正如预期的那样,随着复合材料中EFB纤维含量的增加,吸湿和失水分析中的值都更高。EFB中的羟基通过形成氢键吸收水分。

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