Melanson R, Rochon F D
Département de Chimie, Université du Québec à Montréal, Canada.
Acta Crystallogr C. 1988 Nov 15;44 ( Pt 11):1893-5. doi: 10.1107/s0108270188007395.
[PtCl2(C6H14OS)2], Mr = 534.48, monoclinic, P2(1)/c, a = 9.092 (2), b = 5.696 (2), c = 19.749 (7) A, beta = 110.63 (3) degrees, V = 957.2 (6) A3, Z = 2, D chi = 1.854 Mg m-3, lambda(Mo K alpha) = 0.71069 A, mu(Mo K alpha) = 7.894 mm-1, F(000) = 520, room temperature, R = 0.047 for 1842 unique observed reflections. The Pt atom is located on a center of symmetry. Pt has trans square-planar coordination and the sulfoxide ligands are bonded through their S atoms. The Pt-Cl bond distances are 2.292 (3) A. The Pt-S bond lengths [2.292 (2) A] are significantly longer than the corresponding distances in the cis isomer. The packing consists of layers of molecules parallel to the ab plane.
[二氯二（己硫醚）铂（II）]，Mr = 534.48，单斜晶系，P2(1)/c，a = 9.092（2），b = 5.696（2），c = 19.749（7）Å，β = 110.63（3）°，V = 957.2（6）ų，Z = 2，Dχ = 1.854 Mg m⁻³，λ（Mo Kα） = 0.71069 Å，μ（Mo Kα） = 7.894 mm⁻¹，F(000) = 520，室温，对于1842个独立观测反射，R = 0.047。铂原子位于对称中心。铂具有反式平面正方形配位，亚砜配体通过其硫原子键合。Pt-Cl键长为2.292（3）Å。Pt-S键长[2.292（2）Å]明显长于顺式异构体中的相应距离。堆积由平行于ab平面的分子层组成。
