顺式-二氯二（苯乙烯基苯并噻唑）铂（II）配合物的结构，一种具有苯乙烯基苯并噻唑配体的铂（II）配合物。
Structure of cis-Pt(asb)2Cl2, a platinum(II) complex with a styrylbenzothiazole ligand.
作者信息
Muir M M, Gomez G, Muir J A, Cadiz M E, Cox O, Barnes C L
机构信息
Department of Chemistry, University of Puerto Rico, Rio Piedras 00931.
出版信息
Acta Crystallogr C. 1988 May 15;44 ( Pt 5):803-6. doi: 10.1107/s0108270187012599.
cis-Bis[2-(2-acetoxystyryl)benzothiazole]dichloroplatinum(II), [PtCl2(C17H13NO2S)2], Mr = 856.7, triclinic, P1, a = 12.145 (6), b = 12.859 (4), c = 11.021 (5) A, alpha = 105.88 (3), beta = 90.64 (4), gamma = 87.64 (4) degrees, V = 1654 (2) A3, Z = 2, D chi = 1.72 g cm-3, lambda(Mo K alpha) = 0.71073 A, mu = 46.1 cm-1, F(000) = 840, T = 296 K, final R = 0.029 for 6121 unique observed reflections. The [PtCl2(asb)2] complex has square-planar geometry about the Pt, with the asb coordinated to the Pt through the N of the thiazole ring. The average Pt-N and Pt-Cl bond distances are 2.035 (1) and 2.287 (5) A. The ligand is non-planar with an average dihedral angle of 36 (3) degrees between the benzothiazole and the benzene rings. The dihedral angles between the platinum coordination plane and the benzothiazole and benzene rings are 78 (4) and 69 (7) degrees respectively. The acetoxybenzene rings in the two ligands have different orientations with respect to the olefin C atoms.
顺式-双[2-(2-乙酰氧基苯乙烯基)苯并噻唑]二氯铂(II)，[PtCl₂(C₁₇H₁₃NO₂S)₂]，Mr = 856.7，三斜晶系，P1，a = 12.145(6)，b = 12.859(4)，c = 11.021(5) Å，α = 105.88(3)，β = 90.64(4)，γ = 87.64(4)°，V = 1654(2) ų，Z = 2，Dχ = 1.72 g cm⁻³，λ(Mo Kα) = 0.71073 Å，μ = 46.1 cm⁻¹，F(000) = 840，T = 296 K，对于6121个独立观测反射，最终R = 0.029。[PtCl₂(asb)₂]配合物中Pt周围具有平面正方形几何构型，asb通过噻唑环的N与Pt配位。平均Pt-N和Pt-Cl键长分别为2.035(1)和2.287(5) Å。配体是非平面的，苯并噻唑环和苯环之间的平均二面角为36(3)°。铂配位平面与苯并噻唑环和苯环之间的二面角分别为78(4)和69(7)°。两个配体中的乙酰氧基苯环相对于烯烃C原子具有不同的取向。
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