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通过热拉伸直接压印制备的具有图案化功能的纤维

Designer patterned functional fibers via direct imprinting in thermal drawing.

作者信息

Wang Zhe, Wu Tingting, Wang Zhixun, Zhang Ting, Chen Mengxiao, Zhang Jing, Liu Lin, Qi Miao, Zhang Qichong, Yang Jiao, Liu Wei, Chen Haisheng, Luo Yu, Wei Lei

机构信息

School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore.

Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing, 100190, China.

出版信息

Nat Commun. 2020 Jul 31;11(1):3842. doi: 10.1038/s41467-020-17674-8.

Abstract

Creating micro/nanostructures on fibers is beneficial for extending the application range of fiber-based devices. To achieve this using thermal fiber drawing is particularly important for the mass production of longitudinally uniform fibers up to tens of kilometers. However, the current thermal fiber drawing technique can only fabricate one-directional micro/nano-grooves longitudinally due to structure elongation and polymer reflow. Here, we develop a direct imprinting thermal drawing (DITD) technique to achieve arbitrarily designed surface patterns on entire fiber surfaces with high resolution in all directions. Such a thermal imprinting process is simulated and confirmed experimentally. Key process parameters are further examined, showing a process feature size as small as tens of nanometers. Furthermore, nanopatterns are fabricated on fibers as plasmonic metasurfaces, and double-sided patterned fibers are produced to construct self-powered wearable touch sensing fabric, revealing the bright future of the DITD technology in multifunctional fiber-based devices, wearable electronics, and smart textiles.

摘要

在纤维上创建微/纳米结构有利于扩展基于纤维的器件的应用范围。利用热纤维拉伸来实现这一点对于大规模生产长达数十公里的纵向均匀纤维尤为重要。然而,由于结构伸长和聚合物回流,当前的热纤维拉伸技术只能纵向制造单向微/纳米凹槽。在此,我们开发了一种直接压印热拉伸(DITD)技术,以在整个纤维表面上以高分辨率在所有方向上实现任意设计的表面图案。对这种热压印过程进行了模拟并通过实验得到证实。进一步研究了关键工艺参数,显示出小至几十纳米的工艺特征尺寸。此外,在纤维上制造了作为等离子体超表面的纳米图案,并生产了双面图案化纤维以构建自供电可穿戴触摸传感织物,揭示了DITD技术在多功能纤维基器件、可穿戴电子设备和智能纺织品中的光明前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ba36/7395721/60a29b2c95cd/41467_2020_17674_Fig1_HTML.jpg

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