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SiO 衬底上 ZnO/ZnS/碳纳米管纳米复合材料的形态、材料及光学性质

Morphological, Material, and Optical Properties of ZnO/ZnS/CNTs Nanocomposites on SiO Substrate.

作者信息

Tsai Yu Sheng, Lin Xin Dai, Chan Wei Lun, Tsai Shang Che, Liao Wei Jen, Wu Yew Chung Sermon, Chen Hsiang

机构信息

Department of Materials Science and Engineering, College of Engineer, National Chiao Tung University, Hsinchu 30050, Taiwan.

Department of Applied Materials and Optoelectronic Engineering, College of Science and Technology, National Chi Nan University, Puli 54561, Taiwan.

出版信息

Nanomaterials (Basel). 2020 Aug 4;10(8):1521. doi: 10.3390/nano10081521.

Abstract

Ultraviolet A light (UV-A, 320-400 nm), which is unblockable by sunscreen, requires careful detection for disease avoidance. In this study, we propose a novel photosensing device capable of detecting UV-A. Cancer-causing UV light can be simultaneously monitored with tiny rapid response sensors for a high carrier transition speed. In our research, a multifunctional ZnO/ZnS nanomaterial hybrid-sprinkled carbon nanotube (CNT) was created for the purpose of fabricating a multipurpose, semiconductorbased application. For our research, ZnO nanorods (NRs) were grown by using a facile hydrothermal method on SiO substrate, then vulcanized to form ZnO/ZnS coreshell nanorods, which were sprinkled with carbon nanotubes (CNTs). Results indicate that SiO2/ZnO/ZnS/CNT structures exhibited a stronger conducting current with and without light than those samples without CNTs. Multiple material characterizations of the nanostructures, including of atomic force microscopy (AFM) surface morphology evaluation, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) indicate that CNTs could be successfully spread on top of the ZnO/ZnS coreshell structures. Furthermore, chemical binding properties, material crystallinity, and optical properties were examined by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), and photoluminescence (PL). Owing to their compact size, simple fabrication, and low cost, ZnO/ZnS coreshell NRs/CNT/SiO-based nanocomposites are promising for future industrial optoelectronic applications.

摘要

紫外线A光(UV-A,320 - 400纳米)无法被防晒霜阻挡,为避免疾病需要对其进行仔细检测。在本研究中,我们提出了一种能够检测UV-A的新型光传感装置。致癌的紫外光可以通过具有高载流子跃迁速度的微型快速响应传感器同时进行监测。在我们的研究中,为了制造一种基于半导体的多功能应用,制备了一种多功能的ZnO/ZnS纳米材料杂化的碳纳米管(CNT)。在本研究中,采用简便的水热法在SiO衬底上生长ZnO纳米棒(NRs),然后硫化形成ZnO/ZnS核壳纳米棒,并在其上撒上碳纳米管(CNTs)。结果表明,与没有CNT的样品相比,SiO2/ZnO/ZnS/CNT结构在有光和无光情况下均表现出更强的传导电流。对纳米结构进行的多种材料表征,包括原子力显微镜(AFM)表面形态评估、扫描电子显微镜(SEM)和透射电子显微镜(TEM)表明,CNT能够成功地铺展在ZnO/ZnS核壳结构之上。此外,通过X射线衍射(XRD)、能量色散光谱(EDS)和光致发光(PL)对化学键合性质、材料结晶度和光学性质进行了研究。由于其尺寸紧凑制造简单且成本低廉,基于ZnO/ZnS核壳NRs/CNT/SiO的纳米复合材料在未来工业光电子应用中具有广阔前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3748/7466500/7823ff5c9345/nanomaterials-10-01521-g001.jpg

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