Cutsail George E
Max Planck Institute for Chemical Energy Conversion, Stiftstraße 34-36, D-45470 Mülheim an der Ruhr, Germany.
Dalton Trans. 2020 Sep 15;49(35):12128-12135. doi: 10.1039/d0dt02436h.
The exploration of heavy main-group radicals is rapidly expanding, for which electron paramagnetic resonance (EPR) spectroscopic characterisation plays a key role. EPR spectroscopy has the capacity to deliver information of the radical's electronic, geometric and bonding structure. Herein, foundations of electron-nuclear hyperfine analysis are detailed before reviewing more recent applications of EPR spectroscopy to As, Sb, and Bi centred radicals. Additional diverse examples of the application of EPR spectroscopy to other heavy main group radicals are highlighted.
对重主族自由基的探索正在迅速扩展，电子顺磁共振（EPR）光谱表征在其中发挥着关键作用。EPR光谱能够提供自由基的电子、几何和键合结构信息。本文在回顾EPR光谱对以砷、锑和铋为中心的自由基的最新应用之前，详细介绍了电子-核超精细分析的基础。还重点介绍了EPR光谱应用于其他重主族自由基的更多不同实例。
