基于硼烯的烷基硼酸盐实现了 Ni/Ir 混合催化。
Boracene-based alkylborate enabled Ni/Ir hybrid catalysis.
机构信息
Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kanazawa 920-1192, Japan.
出版信息
Org Biomol Chem. 2020 Sep 14;18(34):6598-6601. doi: 10.1039/d0ob01610a. Epub 2020 Aug 19.
PMID:32812987
Abstract
Boracene-based alkylborate enabled visible light-mediated metallaphotoredox catalysis. The directly excited borate was easily oxidatively quenched by an excited Ir photoredox catalyst. Ni/Ir hybrid catalysis afforded the products under significantly low irradiance.
摘要
基于硼烯的烷基硼酸盐实现了可见光介导的金属光氧化还原催化。直接激发的硼酸盐很容易被激发的铱光氧化还原催化剂氧化猝灭。在镍/铱混合催化下，在显著低辐照度下即可得到产物。
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