Department of Chemistry, Center for Functional Materials, Wake Forest University, 455 Vine Street, Winston-Salem, NC 27101, USA.
Molecules. 2020 Aug 16;25(16):3740. doi: 10.3390/molecules25163740.
Boron and silicon-substituted 1,3-dienes and boron and silicon-substituted alkenes and alkynes have been known for years and the last 10 years have seen a number of new reports of their preparation and use in Diels-Alder reactions. This review first covers boron-substituted dienes and dienophiles and then moves on to discuss silicon-substituted dienes and dienophiles.
硼和硅取代的 1,3-二烯以及硼和硅取代的烯烃和炔烃已经为人所知多年，在过去的 10 年中，人们已经报道了它们在 Diels-Alder 反应中的制备和应用的一些新方法。本综述首先涵盖了硼取代的二烯和亲二烯体，然后继续讨论硅取代的二烯和亲二烯体。
