钯催化的环丙烯对映选择性氢烷氧基化反应。
Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes.
作者信息
Dian Longyang, Marek Ilan
机构信息
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Technion City, Haifa, 32000, Israel.
出版信息
ACS Catal. 2020 Jan 17;10(2):1289-1293. doi: 10.1021/acscatal.9b04960. Epub 2019 Dec 26.
Abstract
We report herein an easy, mild, and robust Pd-catalyzed enantioselective hydroalkynylation reaction of achiral cyclopropenes. Commercially available Pd(acac) and ()-DM-BINAP proved to be the best combination to reach high diastereo- and enantioselectivities.
摘要
我们在此报告一种简便、温和且高效的钯催化非手性环丙烯对映选择性氢炔基化反应。市售的钯（乙酰丙酮）配合物和（）-二甲基联萘二膦被证明是实现高非对映选择性和对映选择性的最佳组合。
Zotero 插件