稀有气体内嵌富勒烯
Noble gas endohedral fullerenes.
作者信息
Jalife Said, Arcudia Jessica, Pan Sudip, Merino Gabriel
机构信息
Departamento de Física Aplicada , Centro de Investigación y de Estudios Avanzados , Antigua carretera a Progreso Km 6, Cordemex, Loma Bonita Xcumpich , 97310 Mérida , Yucatán , Mexico . Email:
Fachbereich Chemie , Philipps-Universität Marburg , Hans-Meerwein-Straße , 35032 Marburg , Germany . Email:
出版信息
Chem Sci. 2020 Jun 16;11(26):6642-6652. doi: 10.1039/d0sc02507k. eCollection 2020 Jul 14.
This review focuses on the available experimental and theoretical investigations on noble gas (Ng) endohedral fullerenes, addressing essential questions related to the mutual effects that confinement of one or more Ng atoms induces on the electronic structure, bonding, and different properties of fullerenes. It also summarizes the different contributions to the mechanisms of formation and decomplexation, the reactivity towards Diels-Alder cycloaddition reactions, the chemical bonding situation of Ng endohedral fullerenes, and the interactions that dominate within these systems.
本综述聚焦于对稀有气体（Ng）内嵌富勒烯的现有实验和理论研究，探讨与一个或多个Ng原子的限制对富勒烯的电子结构、键合及不同性质所产生的相互影响相关的关键问题。它还总结了对形成和解离机制、对狄尔斯-阿尔德环加成反应的反应性、Ng内嵌富勒烯的化学键情况以及这些体系中占主导地位的相互作用的不同贡献。
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