Department of Atmospheric Science, University of Wyoming, 1000 E University Ave, Laramie, Wyoming 82071, United States.
Environmental Defense Fund, 301 Congress Avenue, Suite 1300, Austin, Texas 78701, United States.
Environ Sci Technol. 2020 Nov 3;54(21):13926-13934. doi: 10.1021/acs.est.0c02927. Epub 2020 Oct 15.
Methane emission fluxes were estimated for 71 oil and gas well pads in the western Permian Basin (Delaware Basin), using a mobile laboratory and an inverse Gaussian dispersion method (OTM 33A). Sites with emissions that were below detection limit (BDL) for OTM 33A were recorded and included in the sample. Average emission rate per site was estimated by bootstrapping and by maximum likelihood best log-normal fit. Sites had to be split into "complex" (sites with liquid storage tanks and/or compressors) and "simple" (sites with only wellheads/pump jacks/separators) categories to achieve acceptable log-normal fits. For complex sites, the log-normal fit depends heavily on the number of BDL sites included. As more BDL sites are included, the log-normal distribution fit to the data is falsely widened, overestimating the mean, highlighting the importance of correctly characterizing low end emissions when using log-normal fits. Basin-wide methane emission rates were estimated for the production sector of the New Mexico portion of the Permian and range from ∼520 000 tons per year, TPY (bootstrapping, 95% CI: 300 000-790 000) to ∼610 000 TPY (log-normal fit method, 95% CI: 330 000-1 000 000). These estimates are a factor of 5.5-9.0 times greater than EPA National Emission Inventory (NEI) estimates for the region.
采用移动实验室和反向高斯扩散方法(OTM 33A),对西二叠纪盆地(特拉华盆地)的 71 个油气井场的甲烷排放通量进行了估算。对于 OTM 33A 低于检测限(BDL)的排放站点进行了记录,并包含在样本中。通过自举法和最大似然最佳对数正态拟合来估计每个站点的平均排放率。站点必须分为“复杂”(有液体储罐和/或压缩机的站点)和“简单”(仅有井口/抽油机/分离器的站点)类别,以获得可接受的对数正态拟合。对于复杂站点,对数正态拟合严重依赖于包含的 BDL 站点数量。随着更多 BDL 站点的加入,对数正态分布对数据的拟合被人为地拓宽,高估了平均值,这突出了在使用对数正态拟合时正确描述低端排放的重要性。估算了新墨西哥州二叠纪盆地生产部门的甲烷排放率,范围从每年约 52 万吨(自举法,95%置信区间:30 万-79 万吨)到每年约 61 万吨(对数正态拟合方法,95%置信区间:33 万-100 万吨)。这些估计值是该地区 EPA 国家排放清单(NEI)估计值的 5.5-9.0 倍。