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废弃材料中的纳米颗粒对超高性能混凝土力学性能、耐久性和微观结构的影响

Influence of Nanoparticles from Waste Materials on Mechanical Properties, Durability and Microstructure of UHPC.

作者信息

Mostafa Sahar A, Faried Ahmed S, Farghali Ahmed A, El-Deeb Mohamed M, Tawfik Taher A, Majer Stanisław, Abd Elrahman Mohamed

机构信息

Department of Civil Engineering, Faculty of Engineering, Beni-Suef University, Beni-Suef 62511, Egypt.

Department of Civil Engineering, Faculty of Engineering, Fayoum University, Fayoum 63514, Egypt.

出版信息

Materials (Basel). 2020 Oct 13;13(20):4530. doi: 10.3390/ma13204530.

Abstract

This investigation presents the influence of various types of nanoparticles on the performance of ultra high performance concrete (UHPC). Three nanoparticles from waste materials include nano-crushed glass, nano-metakaolin, nano-rice husk ash were prepared using the milling technique. In addition, nano-silica prepared using chemical method at the laboratory is implemented to compare the performance. Several UHPC mixes incorporating different dosages of nanoparticles up to 5% are prepared and tested. Mechanical properties, durability as well as the microstructure of UHPC mixes have been evaluated in order to study the influence of nanoparticles on the hardened characteristics of UHPC. The experimental results showed that early strength is increased by the incorporation of nanomaterials, as compared to the reference UHPC mix. The incorporation of 3% nano-rice husk ash produced the highest compressive strength at 91 day. Microstructural measurements using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Analysis (EDX), and Thermogravimetric Analysis (TGA) confirm the role of nanomaterials in densifying the microstructure, reducing calcium hydroxide content as well as producing more C-S-H, which improves the strength and reduces the absorption of UHPC. Nanoparticles prepared from waste materials by the milling technique are comparable to chemically prepared nanosilica in improving mechanical properties, refining the microstructure and reducing the absorption of UHPC.

摘要

本研究展示了各类纳米颗粒对超高性能混凝土(UHPC)性能的影响。利用研磨技术制备了三种由废料制成的纳米颗粒,包括纳米碎玻璃、纳米偏高岭土、纳米稻壳灰。此外,还采用了实验室化学方法制备的纳米二氧化硅来进行性能对比。制备并测试了几种掺入不同剂量(最高达5%)纳米颗粒的UHPC混合料。为研究纳米颗粒对UHPC硬化特性的影响,对UHPC混合料的力学性能、耐久性以及微观结构进行了评估。实验结果表明,与参考UHPC混合料相比,掺入纳米材料可提高早期强度。掺入3%纳米稻壳灰在91天时产生了最高抗压强度。使用扫描电子显微镜(SEM)、能量色散X射线分析(EDX)和热重分析(TGA)进行的微观结构测量证实了纳米材料在致密化微观结构、降低氢氧化钙含量以及生成更多C-S-H方面的作用,这提高了强度并降低了UHPC的吸水率。通过研磨技术由废料制备的纳米颗粒在改善力学性能、细化微观结构和降低UHPC吸水率方面与化学制备的纳米二氧化硅相当。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c18/7600628/46b4f4c0a02b/materials-13-04530-g001.jpg

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