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对映选择性光催化的最新进展。

Recent developments in enantioselective photocatalysis.

作者信息

Prentice Callum, Morrisson James, Smith Andrew D, Zysman-Colman Eli

机构信息

Organic Semiconductor Centre, EaStCHEM, School of Chemistry, University of St Andrews, North Haugh, Fife, Scotland, KY16 9ST, United Kingdom.

Pharmaceutical Sciences, IMED Biotech Unit, AstraZeneca, Macclesfield SK102NA, United Kingdom.

出版信息

Beilstein J Org Chem. 2020 Sep 29;16:2363-2441. doi: 10.3762/bjoc.16.197. eCollection 2020.

Abstract

Enantioselective photocatalysis has rapidly grown into a powerful tool for synthetic chemists. This review describes the various strategies for creating enantioenriched products through merging enantioselective catalysis and photocatalysis, with a focus on the most recent developments and a particular interest in the proposed mechanisms for each. With the aim of understanding the scope of each strategy, to help guide and inspire further innovation in this field.

摘要

对映选择性光催化已迅速发展成为合成化学家的一项强大工具。本综述描述了通过将对映选择性催化与光催化相结合来制备对映体富集产物的各种策略,重点关注最新进展以及对每种策略所提出机制的特别兴趣。目的是了解每种策略的适用范围,以帮助指导和激发该领域的进一步创新。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aeb8/7537410/47dd78e4327c/Beilstein_J_Org_Chem-16-2363-g002.jpg

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