Kora Youssef, Boninsegni Massimo, Son Dam Thanh, Zhang Shiwei
Department of Physics, University of Alberta, Edmonton, AB T6G 2E1, Canada;
Department of Physics, University of Alberta, Edmonton, AB T6G 2E1, Canada.
Proc Natl Acad Sci U S A. 2020 Nov 3;117(44):27231-27237. doi: 10.1073/pnas.2017646117. Epub 2020 Oct 21.
We present a comprehensive theoretical study of the phase diagram of a system of many Bose particles interacting with a two-body central potential of the so-called Lennard-Jones form. First-principles path-integral computations are carried out, providing essentially exact numerical results on the thermodynamic properties. The theoretical model used here provides a realistic and remarkably general framework for describing simple Bose systems ranging from crystals to normal fluids to superfluids and gases. The interplay between particle interactions on the one hand and quantum indistinguishability and delocalization on the other hand is characterized by a single quantumness parameter, which can be tuned to engineer and explore different regimes. Taking advantage of the rare combination of the versatility of the many-body Hamiltonian and the possibility for exact computations, we systematically investigate the phases of the systems as a function of pressure (P) and temperature (T), as well as the quantumness parameter. We show how the topology of the phase diagram evolves from the known case of He, as the system is made more (and less) quantum, and compare our predictions with available results from mean-field theory. Possible realization and observation of the phases and physical regimes predicted here are discussed in various experimental systems, including hypothetical muonic matter.
我们对由许多玻色子组成的系统的相图进行了全面的理论研究,该系统与具有所谓 Lennard-Jones 形式的两体中心势相互作用。进行了第一性原理路径积分计算,给出了关于热力学性质的基本精确的数值结果。这里使用的理论模型为描述从晶体到正常流体、超流体和气体等简单玻色子系统提供了一个现实且非常通用的框架。一方面粒子间相互作用与另一方面量子不可区分性和离域性之间的相互作用由一个单一的量子参数表征,该参数可被调节以设计和探索不同的状态。利用多体哈密顿量的通用性与精确计算可能性的罕见结合,我们系统地研究了系统的相作为压力(P)、温度(T)以及量子参数的函数。我们展示了随着系统量子特性增强(和减弱),相图的拓扑结构如何从已知的氦的情况演变,并将我们的预测与平均场理论的现有结果进行比较。在包括假想的μ子物质在内的各种实验系统中讨论了这里预测的相和物理状态的可能实现与观测。