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最活泼无机阳离子对L-赖氨酸盐酸盐晶体光学和生物活性的影响。

Influence of most reactive inorganic cation in the optical and biological activities of L-Lysine monohydrochloride crystal.

作者信息

Aneeba B, Ashvin Santhia S V, Vinu S, Christy R Sheela, Al Farraj Dunia A, Alkubaisi Noorah A

机构信息

Department of Physics and Research Centre, Nesamony Memorial Christian College, Marthandam,Affiliated to Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli, TamilNadu, India.

Department of Physics, Government Arts and Science College, Nagercoil, Tamil Nadu 629004, India.

出版信息

Saudi J Biol Sci. 2020 Nov;27(11):2961-2967. doi: 10.1016/j.sjbs.2020.07.018. Epub 2020 Jul 18.

Abstract

Slow evaporation method was used to grow the pure and K ion doped L-Lysine monohydrochloride (L-LMHCL) crystals which has optical and antibiotic applications. The space group, structure and slight shifting of peaks are confirmed using single crystal XRD and the powder XRD. The FTIR analysis also shows that the K doped L-LMHCL has a slight shifting in the spectrum which indicates the functional group of L-LMHCL and the interaction between the K ions. The existence of K ion in the doped crystal is assured by the presence of potassium in the EDAX spectrum. The wide optical band gap was found for pure and K doped crystal using UV spectra and these are utilized in optoelectronic and nonlinear applications. The Kurtz Perry technique specified the NLO property of grown crystals. The dielectric property crystals was studied by varying the temperature. As a result, the highest dielectric constant is observed in doped crystal. An antibacterial activity against certain bacteria like E-coli, pseudomonas aeruginosa and staphylococcus aureus are provided by mm range for the grown crystals.

摘要

采用缓慢蒸发法生长了具有光学和抗生素应用的纯的及钾离子掺杂的L-赖氨酸盐酸盐(L-LMHCL)晶体。使用单晶X射线衍射仪(XRD)和粉末XRD确定了空间群、结构以及峰的轻微位移。傅里叶变换红外光谱(FTIR)分析还表明,钾掺杂的L-LMHCL在光谱中有轻微位移,这表明了L-LMHCL的官能团以及钾离子之间的相互作用。能谱分析(EDAX)谱中钾的存在确保了掺杂晶体中钾离子的存在。利用紫外光谱发现纯晶体和钾掺杂晶体具有较宽的光学带隙,这些带隙可用于光电子和非线性应用。库尔茨-佩里技术确定了生长晶体的非线性光学(NLO)性质。通过改变温度研究了晶体的介电性质。结果表明,掺杂晶体中观察到最高的介电常数。生长的晶体在毫米范围内对某些细菌如大肠杆菌、铜绿假单胞菌和金黄色葡萄球菌具有抗菌活性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cc3c/7569147/8e377dbcade8/gr1.jpg

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