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环氧丙烷封端对聚亚烷基二醇胺化反应的影响。

Effects of Propylene Oxide End Capping on Amination of Polyalkylene Glycols.

作者信息

Kim Kyungjun, Kang Dong Woo, Im Hyun Gyu, Choi Youngheon, Lee Jae W

机构信息

Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291, Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea.

LOTTE Chemical R&D Center, 115, Gajeongbuk-ro, Yuseong-gu, Daejeon 34110, Republic of Korea.

出版信息

ACS Omega. 2020 Sep 22;5(41):26545-26550. doi: 10.1021/acsomega.0c03295. eCollection 2020 Oct 20.

DOI:10.1021/acsomega.0c03295
PMID:33110982
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7581240/
Abstract

Polyalkylene glycols with two different end-capping groups of ethylene oxide (EO) and propylene oxide (PO) were used for amination to produce polyetheramine (PEA) on cobalt-based catalysts. Although it is known that the amination of secondary alcohol is more difficult than that of primary alcohol, PO end-capped block copolymers showed remarkably enhanced activity toward PEA and selectivity toward the primary amine compared to EO end-capped block copolymers.

摘要

将具有环氧乙烷（EO）和环氧丙烷（PO）两种不同封端基团的聚亚烷基二醇用于胺化反应，以在钴基催化剂上制备聚醚胺（PEA）。虽然已知仲醇的胺化比伯醇更困难，但与EO封端的嵌段共聚物相比，PO封端的嵌段共聚物对PEA表现出显著增强的活性和对伯胺的选择性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/ae9da2cfa99d/ao0c03295_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/69992f65d1a9/ao0c03295_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/35c154e11854/ao0c03295_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/e03475a92746/ao0c03295_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/ae9da2cfa99d/ao0c03295_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/69992f65d1a9/ao0c03295_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/35c154e11854/ao0c03295_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/e03475a92746/ao0c03295_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd4e/7581240/ae9da2cfa99d/ao0c03295_0004.jpg

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本文引用的文献

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