Uwaya Gloria E, Fayemi Omolola E, Sherif El-Sayed M, Junaedi Harri, Ebenso Eno E
Department of Chemistry, Faculty of Natural and Agricultural Sciences, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa.
Material Science Innovation and Modelling (MaSIM) Research Focus Area, Faculty of Natural and Agricultural Sciences, North-West University (Mafikeng Campus), Private Bag X2046, Mmabatho 2735, South Africa.
Materials (Basel). 2020 Oct 31;13(21):4894. doi: 10.3390/ma13214894.
Less toxic, environmentally safe green-mediated iron (III) oxide nanoparticles (FeO-NP) synthesized using () leaf (FeO-NPL) and flower (FeO-NPF) extracts is reported in this work for the first time. Total flavonoids and phenols present in the plant extracts were determined. Characterization of the nanoparticles was carried out using Fourier transform infrared (FTIR) spectroscopy, ultraviolet-visible spectroscopy (UV-VIS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Malvern zeta sizer. Other properties of the nanoparticles were investigated using the thermogravimetric analyser and cyclic voltammetry. The average particle sizes obtained for FeO-NPL and FeO-NPF were 17.91 nm and 27.93 nm, respectively. FeO-NPL exhibited an excellent electrochemical activity when compared with FeO-NPF based on a stability study using cyclic voltammetry and regression value. Additionally, FeO-NPF displayed excellent antimicrobial activity against , , and with zones of inhibition of 13, 15, and 25 mm, respectively. Simple, cheap, and less toxic green-mediated iron (III) oxide nanoparticles synthesized from leaf (FeO-NPL) and flower (FeO-NPF) extracts hold the potential of being used to control the activity of pathogenic bacteria of health importance and as an electrochemical sensor for both biological and environmental analytes.
本文首次报道了使用()叶(FeO-NPL)和花(FeO-NPF)提取物合成的毒性较小、环境安全的绿色介导氧化铁纳米颗粒(FeO-NP)。测定了植物提取物中总黄酮和酚类物质的含量。使用傅里叶变换红外(FTIR)光谱、紫外可见光谱(UV-VIS)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)和马尔文zeta粒度分析仪对纳米颗粒进行了表征。使用热重分析仪和循环伏安法研究了纳米颗粒的其他性质。FeO-NPL和FeO-NPF的平均粒径分别为17.91 nm和27.93 nm。基于循环伏安法和回归值的稳定性研究,与FeO-NPF相比,FeO-NPL表现出优异的电化学活性。此外,FeO-NPF对、和显示出优异的抗菌活性,抑菌圈分别为13、15和25 mm。由叶(FeO-NPL)和花(FeO-NPF)提取物合成的简单、廉价且毒性较小的绿色介导氧化铁纳米颗粒具有控制对健康重要的致病细菌活性的潜力,并可作为生物和环境分析物的电化学传感器。