Chen Chaoyue, Wang Xin, Yang Tinghai
School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, China.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China.
Front Chem. 2020 Sep 23;8:551159. doi: 10.3389/fchem.2020.551159. eCollection 2020.
The synergistic combination of visible-light-induced photoredox catalysis with hypervalent iodine(III) reagents (HIRs) represents a particularly important achievement in the field of hypervalent iodine chemistry, and numerous notable organic transformations were achieved in a mild and environmentally benign fashion. This account intends to summarize recent synthetic applications of HIRs in visible-light-induced photoredox catalysis, and they are organized in terms of the photochemical roles of HIRs played in reactions.
可见光诱导的光氧化还原催化与高价碘(III)试剂(HIRs)的协同结合是高价碘化学领域一项尤为重要的成果,并且以温和且环境友好的方式实现了众多引人注目的有机转化。本综述旨在总结HIRs在可见光诱导的光氧化还原催化中的近期合成应用,并根据HIRs在反应中所起的光化学作用进行整理。