College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, China.
Chem Soc Rev. 2021 Jan 7;50(1):589-618. doi: 10.1039/d0cs00642d. Epub 2020 Nov 11.
Imidazolium based receptors selectively recognize anions, and have received more and more attention. In 2006 and 2010, we reviewed the mechanism and progress of imidazolium salt recognition of anions, respectively. In the past ten years, new developments have emerged in this area, including some new imidazolium motifs and the identification of a wider variety of biological anions. In this review, we discuss the progress of imidazolium receptors for the recognition of anions in the period of 2010-2019 and highlight the trends in this area. We first classify receptors based on motifs, including some newly emerging receptors, as well as new advances in existing receptor types at this stage. Then we discuss separately according to the types of anions, including ATP, GTP, DNA and RNA.
基于咪唑的受体对阴离子具有选择性识别能力,因此受到了越来越多的关注。2006 年和 2010 年,我们分别综述了咪唑盐识别阴离子的机制和进展。在过去的十年中,该领域出现了一些新的发展,包括一些新的咪唑基元和对更多种类生物阴离子的识别。在本文综述中,我们讨论了 2010-2019 年间,关于阴离子识别的咪唑受体的研究进展,并强调了该领域的发展趋势。我们首先根据基序对受体进行分类,包括一些新出现的受体,以及现阶段现有受体类型的新进展。然后我们根据阴离子的类型进行分别讨论,包括 ATP、GTP、DNA 和 RNA。