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FeO@GlcA@Cu-MOF：一种可回收的磁性金属有机骨架催化剂，用于腈的水合、异硫氰酸酯、异氰酸酯和异氰化物的还原。

FeO@GlcA@Cu-MOF: A Magnetic Metal-Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides.

机构信息

Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran.

Department of Chemistry, Ilam University, and P.O. Box 69315516, Ilam, Iran.

出版信息

ACS Comb Sci. 2020 Dec 14;22(12):902-909. doi: 10.1021/acscombsci.0c00178. Epub 2020 Nov 13.

DOI:10.1021/acscombsci.0c00178
PMID:33186013
Abstract

A novel magnetic metal-organic framework (FeO@GlcA@Cu-MOF) has been prepared and characterized by spectroscopic, microscopic, and magnetic techniques. This magnetically separable catalyst exhibited high catalytic activity for nitrile hydration and the ability to reduce isothiocyanates, isocyanates, and with excellent activity and selectivity without any additional reducing agent.

摘要

一种新型的磁性金属有机骨架（FeO@GlcA@Cu-MOF）已通过光谱、显微镜和磁性技术进行了制备和表征。这种可分离的磁性催化剂对腈水合具有很高的催化活性，并且能够在没有任何额外还原剂的情况下，有效地将异硫氰酸酯、异氰酸酯和还原为相应的胺，具有出色的活性和选择性。

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