Kumar Sumit, Padala Kishor
Department of Chemistry, School of Advanced Science, Vellore Institute of Technology, Katpadi, Vellore, Tamil Nadu 632014, India.
Chem Commun (Camb). 2020 Dec 8;56(96):15101-15117. doi: 10.1039/d0cc06036d.
Transition metal-free organic transformations using K2S2O8 is one of the most efficient methods for the formation of carbon-carbon/carbon-heteroatom bond in organic synthesis. K2S2O8-mediated transformations provide a cost-effective and green method for these type of transformations. In addition, these reaction methods are alternatives for many metal-mediated/catalyzed reactions. This article mainly describes the recent advances in K2S2O8-mediated cyclization/coupling reactions via oxidative transformation in organic synthesis in the last few years.
使用过二硫酸钾（K2S2O8）的无过渡金属有机转化是有机合成中形成碳-碳/碳-杂原子键最有效的方法之一。K2S2O8介导的转化为这类转化提供了一种经济高效且绿色的方法。此外，这些反应方法是许多金属介导/催化反应的替代方法。本文主要描述了近年来K2S2O8通过氧化转化介导的有机合成中环化/偶联反应的最新进展。
