Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, P.O. Box 94157, 1090 GD Amsterdam, The Netherlands.
Chem Soc Rev. 2021 Jan 7;50(1):87-101. doi: 10.1039/d0cs01150a. Epub 2020 Nov 19.
There is a clear and pressing need to better manage our planet's resources. Phosphorus is a crucial element for life, but the natural phosphorus cycle has been perturbed to such an extent that humanity faces two dovetailing problems: the dwindling supply of phosphate rock as a resource, and the overabundance of phosphate in water systems leading to eutrophication. This Tutorial Review will explore the current routes to industrial phosphorus compounds, and innovative academic routes towards accessing these same products in a more sustainable manner. It will then describe the many ways that useful phosphate can be recovered from waste streams, and how it can be recycled and used as a resource for new products. Finally, we will briefly discuss the barriers that have thus far prevented the widespread adoption of these technologies, and how we can close the loop to establish a modern phosphorus cycle.
人类显然迫切需要更好地管理地球的资源。磷是生命的关键要素,但自然界的磷循环已被严重扰乱,人类面临着两个相互关联的问题:磷矿石资源日益减少,以及水体中磷过度富集导致的富营养化。本综述将探讨当前工业磷化合物的生产途径,以及学术界在更可持续地获取这些产品方面的创新途径。然后,将描述从废物流中回收有用磷的多种方法,以及如何对其进行回收再利用,将其作为新产品的资源。最后,简要讨论迄今为止阻碍这些技术广泛应用的障碍,以及如何建立现代磷循环来解决这些问题。