Bertau Martin, Wellmer Friedrich-W, Scholz Roland W, Mew Michael, Zenk Lukas, Aubel Ines, Fröhlich Peter, Raddant Matthias, Steiner Gerald
Institute of Chemical Technology, Freiberg University of Mining and Technology, Lessingstraße 45, 09599, Freiberg, Germany.
Academy of Geosciences and Geotechnology, P.O. Box 2538, 38678, Clausthal-Zellerfeld, Germany.
ChemSusChem. 2025 Feb 1;18(3):e202401155. doi: 10.1002/cssc.202401155. Epub 2024 Nov 28.
This paper examines the need for innovation in phosphorus fertilizer production. An important area requiring action is the use of sulfuric acid in the wet chemical process (WCP), which is the dominant process in phosphate fertilizer production. About 50 % of the sulfuric acid produced worldwide is used for fertilizers, and ~95 % of the world's fertilizers are based on sulfuric acid. The latter is almost exclusively a by-product of gas and oil production, so the production of conventional P fertilizer is largely dependent on the availability of oil and gas. In addition to rendering P fertilizer production independent of fossil raw materials, energy consumption, CO emissions, phosphogypsum production and water consumption should also be considered. With the example of the PARFORCE process and the Improved Hard Process (IHP), new non-sulfuric acid-based alternatives are discussed with respect to overcoming the drawbacks of the classical WCP by being completely independent of fossil sources, working with renewable energies as the sole energy source, and the option of using seawater instead of fresh water. These new processes adhere to the principles of climate neutrality, zero waste production, low CO footprint, water conservation, renewable energy use, and energy and resource efficiency. This demonstrates what sustainable innovation can look like from a production perspective. The discussion will focus on whether current incentives are sufficient to realize the sustainability innovations discussed.
本文探讨了磷肥生产中创新的必要性。一个需要采取行动的重要领域是湿法化学工艺(WCP)中硫酸的使用,该工艺是磷肥生产的主导工艺。全球生产的硫酸约有50%用于肥料,全球约95%的肥料以硫酸为基础。后者几乎完全是天然气和石油生产的副产品,因此传统磷肥的生产在很大程度上依赖于油气的供应。除了使磷肥生产独立于化石原料外,还应考虑能源消耗、碳排放、磷石膏生产和用水情况。以PARFORCE工艺和改进硬法工艺(IHP)为例,讨论了新的非硫酸基替代方案,这些方案克服了传统湿法化学工艺的缺点,完全独立于化石资源,以可再生能源作为唯一能源,并可选择使用海水而非淡水。这些新工艺遵循气候中和、零废物生产、低碳足迹、节水、可再生能源利用以及能源和资源效率的原则。这展示了从生产角度看可持续创新可能是什么样的。讨论将集中于当前的激励措施是否足以实现所讨论的可持续创新。