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将塑料废物升级为荧光碳点:一种环保的转化方法,可将生物相容性 C 点转化为具有潜在分析应用前景的 C 点。

Upcycling of plastic waste into fluorescent carbon dots: An environmentally viable transformation to biocompatible C-dots with potential prospective in analytical applications.

机构信息

Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh 160014, India.

Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh 160014, India.

出版信息

Waste Manag. 2021 Feb 1;120:675-686. doi: 10.1016/j.wasman.2020.10.038. Epub 2020 Nov 20.

Abstract

The profitable impact on ecological system made the upcycling of plastic waste as one of the captivating issues in scientific world. The current work highlights the sustainable approach to transform the plastic waste comprises of bottles, used cups and polyethylene bags via simple heating to fluorescent carbon dots (C-dots). The obtained C-dots have displayed the absorption peaks around at 260 nm with size ranging between 5 and 30 nm. The upcycling has produced the structural changes in plastic waste and affected the optical properties of C-dots. The three types of used plastic waste as precursor have displayed excellent emission properties with peak positioned around 422 nm and quantum yield (QY) values ∼62, 65 and 64% for C-dots generated from plastic polybags, cups and bottles (P-CDs, C-CDs and B-CDs) respectively. The toxicity profiling of C-dots has been successfully tested by employing multi-assay biocompatible activities i.e. antibacterial and antifungal activities. The potential prospective of C-dots derived from plastic waste have further been explored in analytical applications involving selective copper metal ion sensing in aqueous media. The outcomes of the current studies have highlighted the potential accomplishment in preserving environment fate and giving response towards the budding social hitch of plastic waste.

摘要

塑料废物的升级再造对生态系统产生了有利影响,成为科学界引人关注的问题之一。本工作重点介绍了一种可持续的方法,通过简单加热,将包含瓶子、用过的杯子和聚乙烯袋在内的塑料废物转化为荧光碳点(C-dots)。所得到的 C-dots 在 260nm 左右显示出吸收峰,尺寸在 5 到 30nm 之间。升级再造导致了塑料废物的结构变化,并影响了 C-dots 的光学性质。三种类型的废旧塑料(塑料袋、杯子和瓶子)作为前体,分别显示出优异的发射性质,其峰值位于 422nm 左右,量子产率(QY)值分别为 62%、65%和 64%,生成的 C-dots 分别为 P-CDs、C-CDs 和 B-CDs。通过采用多指标生物相容性分析,成功测试了 C-dots 的毒性特征,包括抗菌和抗真菌活性。进一步探索了源自塑料废物的 C-dots 在分析应用中的潜在前景,涉及在水相中对铜金属离子的选择性传感。当前研究的结果强调了在保护环境命运和应对塑料废物日益增长的社会问题方面取得的潜在成就。

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