Belich Nikolai, Udalova Natalia, Semenova Anna, Petrov Andrey, Fateev Sergey, Tarasov Alexey, Goodilin Eugene
Department of Materials Science, Lomonosov Moscow State University, Moscow, Russia.
Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia.
Front Chem. 2020 Nov 2;8:550625. doi: 10.3389/fchem.2020.550625. eCollection 2020.
Widely spread crystal lattices of perovskites represent a natural flexible platform for chemical design of various advanced functional materials with unique features. An interplay between chemical bonding, defects and crystallochemical peculiarities makes the perovskite structure a "LEGO designer" utilizing natural features of chemical elements of the renowned Mendeleev's Periodic Table (PTE) celebrating its 150-year anniversary. In this mini-review, crystal chemistry and bonding features, physical and functional properties, preparation methods and tuning functional properties with periodicity "tools" of the PTE will be exemplified for legendary families of high-temperature superconductive cuprates, colossal magnetoresistive manganites and hybrid lead halides for a new generation of solar cells.
广泛分布的钙钛矿晶格是用于设计具有独特特性的各种先进功能材料的天然柔性平台。化学键合、缺陷和晶体化学特性之间的相互作用使钙钛矿结构成为一个“乐高设计师”，它利用著名的门捷列夫元素周期表（PTE）中化学元素的自然特性，而今年恰逢该周期表诞生150周年。在这篇小型综述中，将以高温超导铜酸盐、巨磁阻锰酸盐和用于新一代太阳能电池的混合铅卤化物等传奇家族为例，阐述晶体化学和键合特征、物理和功能特性、制备方法以及利用PTE的周期性“工具”调节功能特性。
